Photons or electrons? A critical comparison of electrochemistry and photoredox catalysis for organic synthesis
Redox processes are at the heart of synthetic methods that rely on either electrochemistry or
photoredox catalysis, but how do electrochemistry and photoredox catalysis compare? Both …
photoredox catalysis, but how do electrochemistry and photoredox catalysis compare? Both …
Photochemical and electrochemical applications of proton-coupled electron transfer in organic synthesis
We present here a review of the photochemical and electrochemical applications of multi-
site proton-coupled electron transfer (MS-PCET) in organic synthesis. MS-PCETs are redox …
site proton-coupled electron transfer (MS-PCET) in organic synthesis. MS-PCETs are redox …
Photoactive copper complexes: properties and applications
J Beaudelot, S Oger, S Perusko, TA Phan… - Chemical …, 2022 - ACS Publications
Photocatalyzed and photosensitized chemical processes have seen growing interest
recently and have become among the most active areas of chemical research, notably due …
recently and have become among the most active areas of chemical research, notably due …
Organic thermally activated delayed fluorescence (TADF) compounds used in photocatalysis
MA Bryden, E Zysman-Colman - Chemical Society Reviews, 2021 - pubs.rsc.org
Organic compounds that show Thermally Activated Delayed Fluorescence (TADF) have
become wildly popular as next-generation emitters in organic light emitting diodes (OLEDs) …
become wildly popular as next-generation emitters in organic light emitting diodes (OLEDs) …
Photoactive Metal-to-Ligand Charge Transfer Excited States in 3d6 Complexes with Cr0, MnI, FeII, and CoIII
Many coordination complexes and organometallic compounds with the 4d6 and 5d6
valence electron configurations have outstanding photophysical and photochemical …
valence electron configurations have outstanding photophysical and photochemical …
Luminescent first-row transition metal complexes
Precious and rare elements have traditionally dominated inorganic photophysics and
photochemistry, but now we are witnessing a paradigm shift toward cheaper and more …
photochemistry, but now we are witnessing a paradigm shift toward cheaper and more …
Strategies and Mechanisms of First-Row Transition Metal-Regulated Radical C–H Functionalization
X Wang, J He, YN Wang, Z Zhao, K Jiang… - Chemical …, 2024 - ACS Publications
Radical C–H functionalization represents a useful means of streamlining synthetic routes by
avoiding substrate preactivation and allowing access to target molecules in fewer steps. The …
avoiding substrate preactivation and allowing access to target molecules in fewer steps. The …
Photophysics and photochemistry with Earth-abundant metals–fundamentals and concepts
C Förster, K Heinze - Chemical Society Reviews, 2020 - pubs.rsc.org
Recent exciting developments in the area of mononuclear photoactive complexes with Earth-
abundant metal ions (Cu, Zr, Fe, Cr) for potential eco-friendly applications in …
abundant metal ions (Cu, Zr, Fe, Cr) for potential eco-friendly applications in …
Potent reductants via electron-primed photoredox catalysis: unlocking aryl chlorides for radical coupling
NGW Cowper, CP Chernowsky… - Journal of the …, 2020 - ACS Publications
We describe a new catalytic strategy to transcend the energetic limitations of visible light by
electrochemically priming a photocatalyst prior to excitation. This new catalytic system is …
electrochemically priming a photocatalyst prior to excitation. This new catalytic system is …
The advent and development of organophotoredox catalysis
T Bortolato, S Cuadros, G Simionato… - Chemical …, 2022 - pubs.rsc.org
In the last decade, photoredox catalysis has unlocked unprecedented reactivities in
synthetic organic chemistry. Seminal advancements in the field have involved the use of well …
synthetic organic chemistry. Seminal advancements in the field have involved the use of well …