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Porphyrin-based frameworks for oxygen electrocatalysis and catalytic reduction of carbon dioxide
Porphyrin-based frameworks, as specific kinds of metal–organic frameworks (MOFs) and
covalent organic frameworks (COFs), have been widely used in energy-related conversion …
covalent organic frameworks (COFs), have been widely used in energy-related conversion …
Oxygen reduction by homogeneous molecular catalysts and electrocatalysts
ML Pegis, CF Wise, DJ Martin, JM Mayer - Chemical Reviews, 2018 - ACS Publications
The oxygen reduction reaction (ORR) is a key component of biological processes and
energy technologies. This Review provides a comprehensive report of soluble molecular …
energy technologies. This Review provides a comprehensive report of soluble molecular …
A pyridinic Fe-N4 macrocycle models the active sites in Fe/N-doped carbon electrocatalysts
Iron-and nitrogen-doped carbon (Fe-NC) materials are leading candidates to replace
platinum catalysts for the oxygen reduction reaction (ORR) in fuel cells; however, their active …
platinum catalysts for the oxygen reduction reaction (ORR) in fuel cells; however, their active …
Energy-related small molecule activation reactions: oxygen reduction and hydrogen and oxygen evolution reactions catalyzed by porphyrin-and corrole-based …
W Zhang, W Lai, R Cao - Chemical reviews, 2017 - ACS Publications
Globally increasing energy demands and environmental concerns related to the use of fossil
fuels have stimulated extensive research to identify new energy systems and economies that …
fuels have stimulated extensive research to identify new energy systems and economies that …
Second sphere effects on oxygen reduction and peroxide activation by mononuclear iron porphyrins and related systems
Activation and reduction of O2 and H2O2 by synthetic and biosynthetic iron porphyrin
models have proved to be a versatile platform for evaluating second-sphere effects deemed …
models have proved to be a versatile platform for evaluating second-sphere effects deemed …
Amine Groups in the Second Sphere of Iron Porphyrins Allow for Higher and Selective 4e–/4H+ Oxygen Reduction Rates at Lower Overpotentials
Iron porphyrins with one or four tertiary amine groups in their second sphere are used to
investigate the electrochemical O2 reduction reaction (ORR) in organic (homogeneous) and …
investigate the electrochemical O2 reduction reaction (ORR) in organic (homogeneous) and …
Molecular electrocatalysts for the oxygen reduction reaction
The past decade has seen considerable growth in the development of materials for fuel cell
electrodes, and there is a desire for active electrocatalysts derived from base metals instead …
electrodes, and there is a desire for active electrocatalysts derived from base metals instead …
Controlling the oxygen reduction selectivity of asymmetric cobalt porphyrins by using local electrostatic interactions
The development and improvement of electrocatalysts for the 4H+/4e–reduction of O2 to
H2O is an ongoing challenge. The addition of ancillary groups (eg, hydrogen bonding …
H2O is an ongoing challenge. The addition of ancillary groups (eg, hydrogen bonding …
Bioinspired N4-metallomacrocycles for electrocatalytic oxygen reduction reaction
Y Li, N Wang, H Lei, X Li, H Zheng, H Wang… - Coordination Chemistry …, 2021 - Elsevier
Oxygen reduction reaction (ORR) is an important process involved in natural and artificial
energy conversion schemes. As inspired by cytochrome c oxidases (CcOs), which are …
energy conversion schemes. As inspired by cytochrome c oxidases (CcOs), which are …
Biochemical and artificial pathways for the reduction of carbon dioxide, nitrite and the competing proton reduction: effect of 2 nd sphere interactions in catalysis
Reduction of oxides and oxoanions of carbon and nitrogen are of great contemporary
importance as they are crucial for a sustainable environment. Substantial research has been …
importance as they are crucial for a sustainable environment. Substantial research has been …