Porphyrin-based frameworks for oxygen electrocatalysis and catalytic reduction of carbon dioxide

Z Liang, HY Wang, H Zheng, W Zhang… - Chemical Society …, 2021 - pubs.rsc.org
Porphyrin-based frameworks, as specific kinds of metal–organic frameworks (MOFs) and
covalent organic frameworks (COFs), have been widely used in energy-related conversion …

Oxygen reduction by homogeneous molecular catalysts and electrocatalysts

ML Pegis, CF Wise, DJ Martin, JM Mayer - Chemical Reviews, 2018 - ACS Publications
The oxygen reduction reaction (ORR) is a key component of biological processes and
energy technologies. This Review provides a comprehensive report of soluble molecular …

A pyridinic Fe-N4 macrocycle models the active sites in Fe/N-doped carbon electrocatalysts

T Marshall-Roth, NJ Libretto, AT Wrobel… - Nature …, 2020 - nature.com
Iron-and nitrogen-doped carbon (Fe-NC) materials are leading candidates to replace
platinum catalysts for the oxygen reduction reaction (ORR) in fuel cells; however, their active …

Energy-related small molecule activation reactions: oxygen reduction and hydrogen and oxygen evolution reactions catalyzed by porphyrin-and corrole-based …

W Zhang, W Lai, R Cao - Chemical reviews, 2017 - ACS Publications
Globally increasing energy demands and environmental concerns related to the use of fossil
fuels have stimulated extensive research to identify new energy systems and economies that …

Second sphere effects on oxygen reduction and peroxide activation by mononuclear iron porphyrins and related systems

S Bhunia, A Ghatak, A Dey - Chemical Reviews, 2022 - ACS Publications
Activation and reduction of O2 and H2O2 by synthetic and biosynthetic iron porphyrin
models have proved to be a versatile platform for evaluating second-sphere effects deemed …

Amine Groups in the Second Sphere of Iron Porphyrins Allow for Higher and Selective 4e/4H+ Oxygen Reduction Rates at Lower Overpotentials

S Bhunia, A Ghatak, A Rana, A Dey - Journal of the American …, 2023 - ACS Publications
Iron porphyrins with one or four tertiary amine groups in their second sphere are used to
investigate the electrochemical O2 reduction reaction (ORR) in organic (homogeneous) and …

Molecular electrocatalysts for the oxygen reduction reaction

S Dey, B Mondal, S Chatterjee, A Rana… - Nature Reviews …, 2017 - nature.com
The past decade has seen considerable growth in the development of materials for fuel cell
electrodes, and there is a desire for active electrocatalysts derived from base metals instead …

Controlling the oxygen reduction selectivity of asymmetric cobalt porphyrins by using local electrostatic interactions

R Zhang, JJ Warren - Journal of the American Chemical Society, 2020 - ACS Publications
The development and improvement of electrocatalysts for the 4H+/4e–reduction of O2 to
H2O is an ongoing challenge. The addition of ancillary groups (eg, hydrogen bonding …

Bioinspired N4-metallomacrocycles for electrocatalytic oxygen reduction reaction

Y Li, N Wang, H Lei, X Li, H Zheng, H Wang… - Coordination Chemistry …, 2021 - Elsevier
Oxygen reduction reaction (ORR) is an important process involved in natural and artificial
energy conversion schemes. As inspired by cytochrome c oxidases (CcOs), which are …

Biochemical and artificial pathways for the reduction of carbon dioxide, nitrite and the competing proton reduction: effect of 2 nd sphere interactions in catalysis

S Amanullah, P Saha, A Nayek, ME Ahmed… - Chemical Society …, 2021 - pubs.rsc.org
Reduction of oxides and oxoanions of carbon and nitrogen are of great contemporary
importance as they are crucial for a sustainable environment. Substantial research has been …