Reactivity of the p‐Cymene‐Ruthenium Complex with Two Phenylamines for Metathesis Polymerization of Norbornene Compared to the Reactivity of Complexes with …
E A. Silva, PHO Santiago, JA Ellena… - European Journal of …, 2024 - Wiley Online Library
Abstract The complexes [RuCl (Cy)(NH2Ph) 2] Cl (1),[RuCl2 (Cy)(NH2Bz)](2), and [RuCl2
(Cy)(NHBz2)](3) were synthesized under identical conditions from [RuCl2 (Cy)] 2, where …
(Cy)(NHBz2)](3) were synthesized under identical conditions from [RuCl2 (Cy)] 2, where …
Hydrogen Bonding Interaction Enabled Ru (III)‐Catalyzed Synthesis of (Multi)‐Substituted Pyridines
Herein, we report a cost‐effective synthesis of various multi‐substituted pyridine derivatives,
especially 2‐aryl pyridines, using secondary alcohols and 1, 3‐diol as the primary feedstock …
especially 2‐aryl pyridines, using secondary alcohols and 1, 3‐diol as the primary feedstock …
Ruthenium and palladium complexes incorporating amino-azo-phenol ligands: Synthesis, characterization, structure and reactivity
P Pattanayak, SP Parua, D Patra, CK Lai… - Inorganica Chimica …, 2015 - Elsevier
Abstract The ligands 2-((2-aminophenyl) diazenyl) phenol, HOL 1-NH 2, 1a; 2-((2-
aminophenyl) diazenyl)-5-methylphenol, HOL 2-NH 2, 1b; and 2-((2-aminophenyl) diazenyl) …
aminophenyl) diazenyl)-5-methylphenol, HOL 2-NH 2, 1b; and 2-((2-aminophenyl) diazenyl) …
Minimalistic Ditopic Ligands: An α‐S, N‐Donor‐Substituted Alkyne as Effective Intermetallic Conjugation Linker
J Rüger, C Timmermann, A Villinger… - … A European Journal, 2016 - Wiley Online Library
The capability of donor‐substituted alkynes to link different metal ions in a side‐on carbon
donor‐chelate coordination mode is extended from the donor centers S and P to the second …
donor‐chelate coordination mode is extended from the donor centers S and P to the second …
Aerial oxidation of protonated aromatic amines. Isolation, x-ray structure, and redox and spectral characteristics of N-containing dyes
This work reports the results of our investigation on the aerial oxidation of aromatic amines
that are promoted by protic acid. While primary aromatic amines produce substituted …
that are promoted by protic acid. While primary aromatic amines produce substituted …
Bis (acetonitrile) bis (acetylacetonato) ruthenium (III) mediated chemical transformations of coordinated 2-methylthioanilide
Chemical reaction of [RuIII (acac) 2 (CH3CN) 2] ClO4 (1) with 2-methylthioaniline, HL1 in
ethanol under basic conditions yielded three new complexes RuII (acac) 2 (L1b)(1b),(L1b= 4 …
ethanol under basic conditions yielded three new complexes RuII (acac) 2 (L1b)(1b),(L1b= 4 …
Complexes of Stable N ‐aryl Radicals and Their Catalytic Applications
N Leconte, F Thomas - Redox‐Active Ligands: Concepts and …, 2024 - Wiley Online Library
Exocyclic N‐aryl radical ligands feature an unpaired electron scattered over both the
coordinating nitrogen (s) and the conjugated aromatic framework. The simplest examples …
coordinating nitrogen (s) and the conjugated aromatic framework. The simplest examples …
Comparative Study on ortho-C–H vs ortho-C–X (X = C, Cl, S) Bond Activation in ortho-Caromatic–N Bond Fusion in Substituted Anilines Using Ruthenium(II) Mediators …
The chemical reactions of a selection of ortho-mono-and disubstituted anilines with two
ruthenium polyene mediator complexes, CpRuIICl (PPh3) 2 (Cp–= cyclopentadienyl anion) …
ruthenium polyene mediator complexes, CpRuIICl (PPh3) 2 (Cp–= cyclopentadienyl anion) …
Reactivity of Rhodium (II) amido/Rhodium (I) aminyl complexes
Reaction of the Rh (II) dimer [LRh] 2 (μ-Br) 2 (L=([2, 6-Me 2 C 6 H 3 NCMe] 2 CH) with the
bulky amide LiNH (2, 6-i Pr 2 C 6 H 3) leads to a monomeric Rh (II) amide with a T-shape N …
bulky amide LiNH (2, 6-i Pr 2 C 6 H 3) leads to a monomeric Rh (II) amide with a T-shape N …
Unusual condensation of ethylene glycol with coordinated 1, 10-phenanthroline-5, 6-dione in [Ru (phen-dione) 2Cl2] and its cyclometallated complex,[Ru (phpy-κ2N …
A novel cyclometallated Ru (II) derivative of 1, 10-phenanthroline-5, 6-dione (phen-
dione),[Ru (phpy-κ2N, C2′)(phen-diox) 2](PF6), where phpy-κ2N, C2′ is 2-phenylpyridine …
dione),[Ru (phpy-κ2N, C2′)(phen-diox) 2](PF6), where phpy-κ2N, C2′ is 2-phenylpyridine …