1, 2-Dicarbofunctionalization of alkenes represents an appealing strategy for chemical bond
formation in organic synthesis, which could enable the rapid construction of molecular …

Catalytic cross-coupling by transition metals has revolutionized the formation of carbon–
carbon bonds in organic synthesis. However, the challenge of forming multiple alkyl–alkyl …

Transition metal–catalyzed cross-coupling reactions are some of the most widely used
methods in chemical synthesis. However, despite notable advantages of iron (Fe) as a …

Multicomponent catalytic processes that can generate multiple C (sp3)–C (sp3) bonds in a
single step under mild conditions, particularly those that employ inexpensive catalysts and …

The intermolecular three-component alkene vicinal dicarbofunctionalization (DCF) reaction
allows installation of two different carbon fragments. Despite extensive investigation into its …

Bicyclo [1.1. 1] pentanes (BCPs) are of great interest to the agrochemical, materials, and
pharmaceutical industries. In particular, synthetic methods to access 1, 3-dicarbosubsituted …

Alkene 1, 2-dicarbofunctionalizations are highly sought-after transformations as they enable
a rapid increase of molecular complexity in one synthetic step. Traditionally, these …

Abstract Efficient methods for synthesizing 1, 2‐aryl (alkenyl) heteroatomic cores,
encompassing heteroatoms such as nitrogen, oxygen, sulfur, and halogens, are of …

We report a general cross-nucleophile alkene alkylarylation that adds two different boronic
acids, an alkyl and an aryl, across a vinylarene to afford 1, 1-diarylalkanes. The high …

A free-radical approach has enabled the development of a synthetically versatile alkyl–
(hetero) arylation of olefins. Alkyl and (hetero) aryl groups were added concurrently to a full …