Challenges and strategies towards single‐crystalline Ni‐rich layered cathodes

L Ni, S Zhang, A Di, W Deng, G Zou… - Advanced energy …, 2022 - Wiley Online Library
The ever‐increasing energy density requirements in electric vehicles (EVs) have boosted
the development of Ni‐rich layered oxide cathodes for state‐of‐the‐art lithium‐ion batteries …

Cobalt‐free cathode materials: families and their prospects

H Zhao, WYA Lam, L Sheng, L Wang… - Advanced Energy …, 2022 - Wiley Online Library
With the rapid growth of global electro‐mobility, the demand for cobalt is rapidly increasing
because it is currently an indispensable component of the cathode materials in lithium‐ion …

Designing cathodes and cathode active materials for solid‐state batteries

P Minnmann, F Strauss, A Bielefeld… - Advanced Energy …, 2022 - Wiley Online Library
Solid‐state batteries (SSBs) currently attract great attention as a potentially safe
electrochemical high‐energy storage concept. However, several issues still prevent SSBs …

Capacity fading mechanisms in Ni-rich single-crystal NCM cathodes

HH Ryu, B Namkoong, JH Kim, I Belharouak… - ACS Energy …, 2021 - ACS Publications
A series of single-crystal, Ni-rich Li [Ni x Co y Mn1–x–y] O2 (NCM) cathodes (x= 0.7, 0.8, and
0.9) with particle diameters of∼ 3 μm are systematically compared with polycrystalline …

Reversible planar gliding and microcracking in a single-crystalline Ni-rich cathode

Y Bi, J Tao, Y Wu, L Li, Y Xu, E Hu, B Wu, J Hu, C Wang… - Science, 2020 - science.org
High-energy nickel (Ni)–rich cathode will play a key role in advanced lithium (Li)–ion
batteries, but it suffers from moisture sensitivity, side reactions, and gas generation. Single …

Fundamental and solutions of microcrack in Ni-rich layered oxide cathode materials of lithium-ion batteries

S Yin, W Deng, J Chen, X Gao, G Zou, H Hou, X Ji - Nano Energy, 2021 - Elsevier
Ni-rich layered transition metal oxide is one of the most promising cathode materials for the
next generation lithium-based automotive batteries due to its excellent electrochemical …

Guidelines and trends for next-generation rechargeable lithium and lithium-ion batteries

F Wu, J Maier, Y Yu - Chemical Society Reviews, 2020 - pubs.rsc.org
Commercial lithium-ion (Li-ion) batteries suffer from low energy density and do not meet the
growing demands of the energy storage market. Therefore, building next-generation …

Oxygen hole formation controls stability in LiNiO2 cathodes

AR Genreith-Schriever, H Banerjee, AS Menon… - Joule, 2023 - cell.com
Ni-rich lithium-ion cathode materials achieve both high voltages and capacities but are
prone to structural instabilities and oxygen loss. The origin of the instability lies in the …

A perspective on single-crystal layered oxide cathodes for lithium-ion batteries

J Langdon, A Manthiram - Energy Storage Materials, 2021 - Elsevier
As the demand for lithium-ion batteries grows exponentially to feed the nascent electric-
vehicle and grid-storage markets, the need for higher energy density and longer cycle life …

Kinetic origin of planar gliding in single-crystalline Ni-rich cathodes

XH Meng, T Lin, H Mao, JL Shi, H Sheng… - Journal of the …, 2022 - ACS Publications
Single-crystalline Ni-rich cathodes with high capacity have drawn much attention for
mitigating cycling and safety crisis of their polycrystalline analogues. However, planar …