Uranium complexes of multidentate N-donor ligands

JL Sessler, PJ Melfi, GD Pantos - Coordination chemistry reviews, 2006 - Elsevier
This review focuses on uranium cation coordination complexes with multidentate nitrogen-
containing ligands appearing in the literature from 2000 to mid-2005, with reports prior to …

The coordination and organometallic chemistry of UI3 and U {N (SiMe3) 2} 3: Synthetic reagents par excellence

RJ Baker - Coordination Chemistry Reviews, 2012 - Elsevier
The coordination and organometallic chemistry of U (III) has been revolutionised by the
preparation of the key starting materials [UI3 (solv) 4](solv= THF, py, 1/2DME),[U {N (SiMe3) …

Uranium (III) Redox Chemistry Assisted by a Hemilabile Bis (phenolate) Cyclam Ligand: Uranium–Nitrogen Multiple Bond Formation Comprising a trans-{RN U (VI) …

L Maria, IC Santos, VR Sousa, J Marcalo - Inorganic Chemistry, 2015 - ACS Publications
A new monoiodide U (III) complex anchored on a hexadentate dianionic 1, 4, 8, 11-
tetraazacyclotetradecane-based bis (phenolate) ligand,[U (κ6-{(tBu2ArO) 2Me2-cyclam}) …

Analysis of uranium azide and nitride complexes by atmospheric pressure chemical ionization mass spectrometry

WJ Evans, KA Miller, JW Ziller, J Greaves - Inorganic chemistry, 2007 - ACS Publications
Atmospheric pressure chemical ionization mass spectrometry (APCI-MS) has been used to
characterize the air-sensitive paramagnetic organouranium azide and nitride complexes …

Synthesis of U (iv) imidos from Tp* 2 U (CH 2 Ph)(Tp*= hydrotris (3, 5-dimethylpyrazolyl) borate) by extrusion of bibenzyl

EM Matson, MG Crestani, PE Fanwick, SC Bart - Dalton Transactions, 2012 - pubs.rsc.org
Addition of organic azides, N3R (R= 2, 4, 6-trimethylphenyl (Mes), phenyl (Ph), 1-adamantyl
(Ad)), to a solution of the uranium (III) alkyl complex, Tp* 2U (CH2Ph)(Tp*= hydrotris (3, 5 …

A short ride on scorpionates: from d-to f-elements

A Paulo, JDG Correia, MPC Campello, I Santos - Polyhedron, 2004 - Elsevier
This paper presents an overview of progress involving group 7 elements and actinides with
scorpionate ligands. This includes oxides, polyhydrides and carbonyls of group 7 elements …

Actinide coordination and organometallic complexes with multidentate polyamido ligands

CE Hayes, DB Leznoff - Coordination Chemistry Reviews, 2014 - Elsevier
Amido-based ligand sets have found considerable use in the active and growing area of
actinide chemistry, forming highly reactive and unusual actinide-containing complexes as a …

Synthesis and structure of diamido ether uranium (iv) and thorium (iv) halide “ate” complexes and their conversion to salt-free bis (alkyl) complexes

KC Jantunen, F Haftbaradaran, MJ Katz… - Dalton …, 2005 - pubs.rsc.org
The high-yield synthesis, spectroscopic and structural determination of three new uranium
(IV) and thorium (IV)“ate” complexes supported by three different diamido ether ligands are …

Uranium (III) Scorpionates:  Synthesis and Structure of [(TpMe2)2U{N(C6H5)2}] and [(TpMe2)2U{N(SiMe3)2}]

MA Antunes, GM Ferrence, Â Domingos… - Inorganic …, 2004 - ACS Publications
Reaction of [(TpMe2) 2UI] with KNR2 (R= C6H5, SiMe3) in tetrahydrofuran (THF) afforded
the monomeric trivalent actinide amide complexes [(TpMe2) 2U {N (C6H5) 2}], 1, and …

Synthesis and characterization of uranium (III) compounds supported by the hydrotris (3, 5-dimethyl-pyrazolyl) borate ligand: Crystal structures of [U (TpMe2) 2 (X)] …

MA Antunes, Â Domingos, IC dos Santos, N Marques… - Polyhedron, 2005 - Elsevier
Reaction of [U (TpMe2) 2 (NR2)](R= Ph, SiMe3) with protic substrates such as 2, 4, 6-
trimethylphenol (HOC6H2-2, 4, 6-Me3), 3, 5-dimethylpyrazole (Hdmpz), 2-mercaptopyridine …