An Isolable Triarylphosphine Radical Cation Electronically Stabilized by Through-Space Radical Delocalization
Synthesis and characterization of a thermally stable triarylphosphine radical cation,[P (8-Br-
C10H6) 3][BArF24]([1][BArF24], BArF24= tetrakis (3, 5-bis (trifluoromethyl) phenyl) borate) …
C10H6) 3][BArF24]([1][BArF24], BArF24= tetrakis (3, 5-bis (trifluoromethyl) phenyl) borate) …
A crystallized view of acid-base chemistry
AR Jupp - Science, 2024 - science.org
Interactions between electron pair acceptors (Lewis acids) and electron pair donors (Lewis
bases) to create bimolecular Lewis adducts are fundamental to understanding and …
bases) to create bimolecular Lewis adducts are fundamental to understanding and …
Can Azomethine Ylides be Considered as Frustrated Lewis Pairs?
Azomethine ylides are typically transient synthons, heavily used in constructing N-
heterocycles by dipolar cycloaddition reactions. We report here a pyridyl-tethered isolable …
heterocycles by dipolar cycloaddition reactions. We report here a pyridyl-tethered isolable …