This third review in a series involving reactions of hydrosilanes and transition metal
complexes and characterization of the products covers the period 2009 thru 2013. After a …

Over the past decade, significant progress has been made in the chemistry of transition
metal complexes supported by multidentate chelate ligands, such as pincer-type ligands, in …

The ability of Lewis acids to coordinate to transition metals as σ-acceptor ligands was
recognized as early as in the 1970's, but so-called Z-type ligands remained curiosities until …

Names: Stradiotto, Mark, author.| Lundgren, Rylan, author. Title: Ligand design in metal
chemistry: reactivity and catalysis/[edited by] Mark Stradiotto, Rylan Lundgren. Description …

In 1961, a report in the Journal of the American Chemical Society detailed the synthesis of a
lemon-yellow compound asssigned as the organometallic complex trans-[IrCl (CO)(PPh3) …

Transition-metal complexes with Si–M bonds are important catalysts for hydrosilylation and
hydrogenation reactions. However, the function of the ligated silicon atom in the …

Over the past decade, the chemistry of σ-accepting or Z-type ligands based on main group
elements has drawn renewed attention because of the realization that their interaction with a …

Up until recently, our understanding of the chemistry resulting from the combination of Lewis
acids and bases had not evolved much since Lewis' time. In large part, the formation of …

Gold (I) chloride complexes are stable, widespread precatalysts that generally require
activation by halide abstraction to display useful catalytic activity. Chloride scavenging is …

Turn on the lantern! The stibine donor ligand of a cationic palladium complex acts as a
Lewis acid and reacts with a fluoride anion to afford the corresponding fluorostiboranyl …