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Recent advances in the polymerization of elemental sulphur, inverse vulcanization and methods to obtain functional Chalcogenide Hybrid Inorganic/Organic Polymers …
Recent developments in the polymerization of elemental sulfur and the preparation of
functional Chalcogenide Hybrid Inorganic/Organic Polymers (CHIPs) are reviewed. CHIPs …
functional Chalcogenide Hybrid Inorganic/Organic Polymers (CHIPs) are reviewed. CHIPs …
Synthesis and applications of polymers made by inverse vulcanization
Elemental sulfur is an abundant and inexpensive chemical feedstock, yet it is underused as
a starting material in chemical synthesis. Recently, a process coined inverse vulcanization …
a starting material in chemical synthesis. Recently, a process coined inverse vulcanization …
Polymerizations with elemental sulfur: from petroleum refining to polymeric materials
The production of elemental sulfur from petroleum refining has created a technological
opportunity to increase the valorization of elemental sulfur by the synthesis of high …
opportunity to increase the valorization of elemental sulfur by the synthesis of high …
On the Mechanism of the Inverse Vulcanization of Elemental Sulfur: Structural Characterization of Poly(sulfur-random-(1,3-diisopropenylbenzene))
Organosulfur polymers, such as those derived from elemental sulfur, are an important new
class of macromolecules that have recently emerged via the inverse vulcanization process …
class of macromolecules that have recently emerged via the inverse vulcanization process …
Catalytic inverse vulcanization
The discovery of inverse vulcanization has allowed stable polymers to be made from
elemental sulfur, an unwanted by-product of the petrochemicals industry. However, further …
elemental sulfur, an unwanted by-product of the petrochemicals industry. However, further …
Chemically induced repair, adhesion, and recycling of polymers made by inverse vulcanization
Inverse vulcanization is a copolymerization of elemental sulfur and alkenes that provides
unique materials with high sulfur content (typically≥ 50% sulfur by mass). These polymers …
unique materials with high sulfur content (typically≥ 50% sulfur by mass). These polymers …
Inverse vulcanized polymers with shape memory, enhanced mechanical properties, and vitrimer behavior
The invention of inverse vulcanization provides great opportunities for generating functional
polymers directly from elemental sulfur, an industrial by‐product. However, unsatisfactory …
polymers directly from elemental sulfur, an industrial by‐product. However, unsatisfactory …
Inverse vulcanized polymers for sustainable metal remediation
Heavy metal exposure has an enormous burden on human health. Current metal removal
technologies require substantial improvements in relation to their efficiency and …
technologies require substantial improvements in relation to their efficiency and …
Structural evolution during inverse vulcanization
Inverse vulcanization exploits S8 to synthesize polysulfides. However, evolution of products
and its mechanism during inverse vulcanization remains elusive. Herein, inverse …
and its mechanism during inverse vulcanization remains elusive. Herein, inverse …
100th anniversary of macromolecular science viewpoint: high refractive index polymers from elemental sulfur for infrared thermal imaging and optics
TS Kleine, RS Glass, DL Lichtenberger… - ACS Macro …, 2020 - ACS Publications
Optical technologies in the midwave and long wave infrared spectrum (MWIR, LWIR) are
important systems for high resolution thermal imaging in near, or complete darkness. While …
important systems for high resolution thermal imaging in near, or complete darkness. While …