Photomediated controlled radical polymerization is a versatile method to prepare, under
mild conditions, various well-defined polymers with complex architecture, such as block and …

Reversible‐deactivation radical polymerizations (RDRPs) have revolutionized synthetic
polymer chemistry. Nowadays, RDRPs facilitate design and preparation of materials with …

Spatial and temporal regulations of ATRP by external stimuli are presented. Various ATRP
techniques, eATRP, photoATRP, and mechanoATRP, are controlled by electrical current …

Approaching 25 years since its invention, atom transfer radical polymerization (ATRP) is
established as a powerful technique to prepare precisely defined polymeric materials. This …

A short review of the role of photocatalysts in photopolymerization reactions is presented. A
special emphasis is placed on photoredox catalysts leading to i) high‐performance initiating …

Advances in controlled radical polymerizations by cobalt complexes have primarily taken
advantage of the reactivity of cobalt as a persistent radical to reversibly deactivate …

Atom transfer radical polymerization (ATRP) is one of the most often used controlled radical
polymerization techniques. It employs very small amounts (ppm) of Cu complexes in the …

In the last two decades, metal-catalyzed controlled radical polymerization (CRP), or atom
transfer radical polymerization (ATRP) has become a ubiquitous tool for the facile synthesis …

Metal complexes are used in numerous chemical and photochemical processes in organic
chemistry. Metal complexes have not been excluded from the interest of polymerists to …

Catalysts are essential for mediating a controlled polymerization in atom transfer radical
polymerization (ATRP). Copper-based catalysts are widely explored in ATRP and are highly …