Spectroscopy and dynamics of the hydrated electron at the water/air interface

CJC Jordan, MP Coons, JM Herbert… - nature …, 2024 - nature.com
The hydrated electron, e–(aq), has attracted much attention as a central species in radiation
chemistry. However, much less is known about e–(aq) at the water/air surface, despite its …

Empirically Optimized One-Electron Pseudopotential for the Hydrated Electron: A Proof-of-Concept Study

P Neupane, DM Bartels… - The Journal of Physical …, 2023 - ACS Publications
Mixed quantum-classical molecular dynamics simulations have been important tools for
studying the hydrated electron. They generally use a one-electron pseudopotential to …

Evaluating the Chemical Reactivity of DFT-Simulated Liquid Water with Hydrated Electrons via the Dual Descriptor

WR Borrelli, X Liu, BJ Schwartz - Journal of Chemical Theory and …, 2024 - ACS Publications
Modeling the various properties of liquid water, particularly its reactivity, has been a
longstanding challenge for simulation methods. Recently, ab initio simulations based on …

Partial Molar Solvation Volume of the Hydrated Electron Simulated Via DFT

WR Borrelli, KJ Mei, SJ Park… - The Journal of Physical …, 2024 - ACS Publications
Different simulation models of the hydrated electron produce different solvation structures,
but it has been challenging to determine which simulated solvation structure, if any, is the …