Thirty years of density functional theory in computational chemistry: an overview and extensive assessment of 200 density functionals

N Mardirossian, M Head-Gordon - Molecular physics, 2017 - Taylor & Francis
In the past 30 years, Kohn–Sham density functional theory has emerged as the most popular
electronic structure method in computational chemistry. To assess the ever-increasing …

Dispersion-corrected mean-field electronic structure methods

S Grimme, A Hansen, JG Brandenburg… - Chemical …, 2016 - ACS Publications
Mean-field electronic structure methods like Hartree–Fock, semilocal density functional
approximations, or semiempirical molecular orbital (MO) theories do not account for long …

Advances in molecular quantum chemistry contained in the Q-Chem 4 program package

Y Shao, Z Gan, E Epifanovsky, ATB Gilbert… - Molecular …, 2015 - Taylor & Francis
A summary of the technical advances that are incorporated in the fourth major release of the
q-Chem quantum chemistry program is provided, covering approximately the last seven …

A look at the density functional theory zoo with the advanced GMTKN55 database for general main group thermochemistry, kinetics and noncovalent interactions

L Goerigk, A Hansen, C Bauer, S Ehrlich… - Physical Chemistry …, 2017 - pubs.rsc.org
We present the GMTKN55 benchmark database for general main group thermochemistry,
kinetics and noncovalent interactions. Compared to its popular predecessor GMTKN30 …

A consistent and accurate ab initio parametrization of density functional dispersion correction (DFT-D) for the 94 elements H-Pu

S Grimme, J Antony, S Ehrlich, H Krieg - The Journal of chemical …, 2010 - pubs.aip.org
The method of dispersion correction as an add-on to standard Kohn–Sham density
functional theory (DFT-D) has been refined regarding higher accuracy, broader range of …

Long-range corrected hybrid density functionals with damped atom–atom dispersion corrections

JD Chai, M Head-Gordon - Physical Chemistry Chemical Physics, 2008 - pubs.rsc.org
We report re-optimization of a recently proposed long-range corrected (LC) hybrid density
functional [J.-D. Chai and M. Head-Gordon, J. Chem. Phys., 2008, 128, 084106] to include …

Density functional theory with London dispersion corrections

S Grimme - Wiley Interdisciplinary Reviews: Computational …, 2011 - Wiley Online Library
Dispersion corrections to standard Kohn–Sham density functional theory (DFT) are
reviewed. The focus is on computationally efficient methods for large systems that do not …

A thorough benchmark of density functional methods for general main group thermochemistry, kinetics, and noncovalent interactions

L Goerigk, S Grimme - Physical Chemistry Chemical Physics, 2011 - pubs.rsc.org
A thorough energy benchmark study of various density functionals (DFs) is carried out with
the new GMTKN30 database for general main group thermochemistry, kinetics and …

[HTML][HTML] Communication: An improved linear scaling perturbative triples correction for the domain based local pair-natural orbital based singles and doubles coupled …

Y Guo, C Riplinger, U Becker, DG Liakos… - The Journal of …, 2018 - pubs.aip.org
In this communication, an improved perturbative triples correction (T) algorithm for domain
based local pair-natural orbital singles and doubles coupled cluster (DLPNO-CCSD) theory …

Perspective: Advances and challenges in treating van der Waals dispersion forces in density functional theory

J Klimeš, A Michaelides - The Journal of chemical physics, 2012 - pubs.aip.org
Electron dispersion forces play a crucial role in determining the structure and properties of
biomolecules, molecular crystals, and many other systems. However, an accurate …