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Aggregation behaviour of pyrene-based luminescent materials, from molecular design and optical properties to application
Molecular aggregates are self-assembled from multiple molecules via weak intermolecular
interactions, and new chemical and physical properties can emerge compared to their …
interactions, and new chemical and physical properties can emerge compared to their …
Recent developments in and perspectives on three-coordinate boron materials: a bright future
The empty pz-orbital of a three-coordinate organoboron compound leads to its electron-
deficient properties, which make it an excellent π-acceptor in conjugated organic …
deficient properties, which make it an excellent π-acceptor in conjugated organic …
Recent advances in catalytic C− H borylation reactions
In the past decades, the iridium-catalyzed C–H bond borylation and other newly discovered
catalytic borylation reactions have received extensive research interests and developed into …
catalytic borylation reactions have received extensive research interests and developed into …
Functionalization of pyrene to prepare luminescent materials—typical examples of synthetic methodology
Pyrene‐based π‐conjugated materials are considered to be an ideal organic electro‐
luminescence material for application in semiconductor devices, such as organic light …
luminescence material for application in semiconductor devices, such as organic light …
The influence of molecular packing on the emissive behavior of pyrene derivatives: mechanoluminescence and mechanochromism
Although some bright, organic mechanoluminescence (ML) luminogens with aggregation‐
induced emission properties and twisted molecular structures are recently reported, those …
induced emission properties and twisted molecular structures are recently reported, those …
C–H borylation: a tool for molecular diversification
Iridium-catalyzed C–H activation and borylation has become as a powerful synthetic tool in
the past few decades because of the widespread applicability and versatility of organoboron …
the past few decades because of the widespread applicability and versatility of organoboron …
Electrophilic C–H borylation of aza [5] helicenes leading to bowl-shaped quasi-[7] circulenes with switchable dynamics
The intrinsic relationship between helicenes and circulenes is of fundamental interest and
importance in molecular engineering. Herein, electrophilic borylation of phenanthroline …
importance in molecular engineering. Herein, electrophilic borylation of phenanthroline …
Electron Delocalization in Reduced Forms of 2-(BMes2)pyrene and 2,7-Bis(BMes2)pyrene
Reduction of 2-(BMes2) pyrene (B 1) and 2, 7-bis (BMes2) pyrene (B 2) gives rise to anions
with extensive delocalization over the pyrenylene bridge and between the boron centers at …
with extensive delocalization over the pyrenylene bridge and between the boron centers at …
Synthesis of substituted pyrenes by indirect methods
The pyrene nucleus is a valuable component for materials, supramolecular and biological
chemistry, due to its photophysical/electronic properties and extended rigid structure …
chemistry, due to its photophysical/electronic properties and extended rigid structure …
Pushing the Ir-catalyzed C–H polyborylation of aromatic compounds to maximum capacity by exploiting reversibility
Small amounts of base (eg, 10% potassium t-butoxide or sodium methoxide) have been
found to promote equilibration of the kinetically favored products from Ir-catalyzed C–H …
found to promote equilibration of the kinetically favored products from Ir-catalyzed C–H …