Polynuclear coordination clusters have become of particular interest in recent times as a
result of their relevance to bioinorganic chemistry and to the special area of molecule-based …

Polymetallic clusters of manganese ions come in a bewildering variety of shapes and sizes,
from simple triangles,[1] cubes,[2] and butterflies,[3] to wheels,[4] discs,[5] rods,[6] truncated …

The first family of rare-earth-based single chain magnets is presented. Compounds of
general formula [M (hfac) 3 (NITPhOPh)], where M= Eu, Gd, Tb, Dy, Ho, Er, or Yb, and …

Polynuclear 3d metal complexes are of interest for various reasons, one of which is the
possibility that they might exhibit high-spin (S) ground states and easy-axis-type magnetic …

High-Spin Molecules: A Novel Cyano-Bridged MnMo Molecular Cluster with a S=51/2 Ground
State and Ferromagnetic Intercluster Ordering at Low Temperatures Financial support by the …

The syntheses and structures of two decametallic mixed-valent Mn supertetrahedra using 2-
amino-2-methyl-1, 3-propanediol (ampH2), two decametallic mixed-valent Mn planar discs …

Reactions of lanthanide (III) nitrates with multi-donor carboxylate ligand in the presence of
oxalate anion afforded four new lanthanide coordination polymers with three dimensional …

Predicting single‐molecule magnets? Magnetic anisotropy, a property that plays a key role
in single‐molecule magnets (SMMs), has been analyzed by using theoretical methods …

Both ferromagnetic and ferroelectric properties were observed in two enantiomerically pure
nanoscale manganese cluster complexes supported by chiral Schiff base ligands, each of …

Publisher Summary This chapter discusses high-nuclearity paramagnetic 3d-metal
complexes with oxygen-and nitrogen-donor ligands. The studies of high-nuclearity iron …