[HTML][HTML] Electronic structure and magnetic anisotropy design of functional metal complexes

A Raza, M Perfetti - Coordination Chemistry Reviews, 2023 - Elsevier
Chemical guidelines to target a well-defined electronic structure and magnetic anisotropy
are of primary importance in physics, chemistry and biology. Our literature overview …

Chirality‐Induced Spin Selectivity: An Enabling Technology for Quantum Applications

A Chiesa, A Privitera, E Macaluso… - Advanced …, 2023 - Wiley Online Library
Molecular spins are promising building blocks of future quantum technologies thanks to the
unparalleled flexibility provided by chemistry, which allows the design of complex structures …

Molecular nanomagnets: a viable path toward quantum information processing?

A Chiesa, P Santini, E Garlatti, F Luis… - Reports on Progress in …, 2024 - iopscience.iop.org
Molecular nanomagnets (MNMs), molecules containing interacting spins, have been a
playground for quantum mechanics. They are characterized by many accessible low-energy …

The critical role of ultra-low-energy vibrations in the relaxation dynamics of molecular qubits

E Garlatti, A Albino, S Chicco, VHA Nguyen… - Nature …, 2023 - nature.com
Improving the performance of molecular qubits is a fundamental milestone towards
unleashing the power of molecular magnetism in the second quantum revolution. Taming …

A Heterometallic Porphyrin Dimer as a Potential Quantum Gate: Magneto‐Structural Correlations and Spin Coherence Properties

D Ranieri, A Privitera, F Santanni… - Angewandte …, 2023 - Wiley Online Library
In the development of two‐qubit quantum gates, precise control over the intramolecular spin‐
spin interaction between molecular spin units plays a pivotal role. A weak but measurable …

Oriented Triplet Excitons as Long-Lived Electron Spin Qutrits in a Molecular Donor–Acceptor Single Cocrystal

JR Palmer, ML Williams, RM Young… - Journal of the …, 2023 - ACS Publications
The photogeneration of multiple unpaired electron spins within molecules is a promising
route to applications in quantum information science because they can be initialized into …

Molecular one‐and two‐qubit systems with very long coherence times

D Schäfter, J Wischnat, L Tesi, JA De Sousa… - Advanced …, 2023 - Wiley Online Library
General‐purpose quantum computation and quantum simulation require multi‐qubit
architectures with precisely defined, robust interqubit interactions, coupled with local …

Room-Temperature Optical Spin Polarization of an Electron Spin Qudit in a Vanadyl-Free Base Porphyrin Dimer

A Privitera, A Chiesa, F Santanni… - Journal of the …, 2024 - ACS Publications
Photoexcited organic chromophores appended to molecular qubits can serve as a source of
spin initialization or multilevel qudit generation for quantum information applications. So far …

Metalloporphyrins as building blocks for quantum information science

F Santanni, A Privitera - Advanced Optical Materials, 2024 - Wiley Online Library
The intrinsic quantum nature of molecules opens exciting opportunities for develo** the
field of quantum information science. In this context, porphyrins stand out as ideal building …

Enhanced coherence by coupling spins through a delocalized π-system: Vanadyl porphyrin dimers

I Pozo, Z Huang, F Lombardi, DI Alexandropoulos… - Chem, 2024 - cell.com
Vanadium (IV) magnetic centers are prime candidates for molecular quantum units. One
long-standing question is how to obtain a scaffold that connects multiple centers and allows …