In recent times, earth-abundant 3d-transition-metal catalysts have attracted much attention in
contemporary catalysis. They have been widely employed as suitable alternatives to their …

Borrowing hydrogen or the hydrogen autotransfer amination is a powerful approach to
create single C–N bonds, starting from stable and readily available substrates: amines and …

In this review, we aim to give an overview of the use of the Borrowing Hydrogen (BH)
methodology with bio-based alcohols. This methodology only forms water as a by-product …

Dual photoredox/nickel-catalysed C–N cross-couplings suffer from low yields for electron-
rich aryl halides. The formation of catalytically inactive nickel-black is responsible for this …

We report herein a well-defined and bench-stable azo-phenolate ligand-coordinated nickel
catalyst which can efficiently execute N-alkylation of a variety of anilines by alcohol. We …

A general cobalt-catalyzed N-alkylation of amines with alcohols by borrowing hydrogen
methodology to prepare different kinds of amines is reported. The optimal catalyst for this …

N-alkylation of anilines by alcohols can be used as an efficient strategy to synthesise a wide
range of secondary amines. In this respect, a hydrogen borrowing methodology has been …

We report a sustainable and eco-friendly approach for selective N-alkylation of various
amines by alcohols, catalyzed by a well-defined Zn (II)-catalyst, Zn (La) Cl2 (1a), bearing a …

A highly sustainable catalytic protocol for the coupling of alcohols and amines for selective
monoalkylated amines using Ni (II)–NΛNΛO pincer type complexes through the borrowing …

The challenge in the C–C cross-coupling of secondary and primary alcohols using
acceptorless dehydrogenation coupling (ADC) is the difficulty in accurately controlling …