Technological innovations in photochemistry for organic synthesis: flow chemistry, high-throughput experimentation, scale-up, and photoelectrochemistry
Photoinduced chemical transformations have received in recent years a tremendous amount
of attention, providing a plethora of opportunities to synthetic organic chemists. However …
of attention, providing a plethora of opportunities to synthetic organic chemists. However …
Machine learning for electrocatalyst and photocatalyst design and discovery
Electrocatalysts and photocatalysts are key to a sustainable future, generating clean fuels,
reducing the impact of global warming, and providing solutions to environmental pollution …
reducing the impact of global warming, and providing solutions to environmental pollution …
A mobile robotic chemist
Technologies such as batteries, biomaterials and heterogeneous catalysts have functions
that are defined by mixtures of molecular and mesoscale components. As yet, this multi …
that are defined by mixtures of molecular and mesoscale components. As yet, this multi …
Computation-based regulation of excitonic effects in donor-acceptor covalent organic frameworks for enhanced photocatalysis
The strong excitonic effects widely exist in polymer-semiconductors and the large exciton
binding energy (E b) seriously limits their photocatalysis. Herein, density functional theory …
binding energy (E b) seriously limits their photocatalysis. Herein, density functional theory …
Particulate photocatalysts for light-driven water splitting: mechanisms, challenges, and design strategies
Q Wang, K Domen - Chemical Reviews, 2019 - ACS Publications
Solar-driven water splitting provides a leading approach to store the abundant yet
intermittent solar energy and produce hydrogen as a clean and sustainable energy carrier. A …
intermittent solar energy and produce hydrogen as a clean and sustainable energy carrier. A …
Molecularly engineered covalent organic frameworks for hydrogen peroxide photosynthesis
M Kou, Y Wang, Y Xu, L Ye, Y Huang… - Angewandte Chemie …, 2022 - Wiley Online Library
Synthesizing H2O2 from water and air via a photocatalytic approach is ideal for efficient
production of this chemical at small‐scale. However, the poor activity and selectivity of the 2 …
production of this chemical at small‐scale. However, the poor activity and selectivity of the 2 …
Generation of long-lived charges in organic semiconductor heterojunction nanoparticles for efficient photocatalytic hydrogen evolution
Organic semiconductor photocatalysts for the production of solar fuels are attractive as they
can be synthetically tuned to absorb visible light while simultaneously retaining suitable …
can be synthetically tuned to absorb visible light while simultaneously retaining suitable …
Advances in conjugated microporous polymers
Conjugated microporous polymers (CMPs) are a unique class of materials that combine
extended π-conjugation with a permanently microporous skeleton. Since their discovery in …
extended π-conjugation with a permanently microporous skeleton. Since their discovery in …
Accelerated synthesis and discovery of covalent organic framework photocatalysts for hydrogen peroxide production
A high-throughput sonochemical synthesis and testing strategy was developed to discover
covalent organic frameworks (COFs) for photocatalysis. In total, 76 conjugated polymers …
covalent organic frameworks (COFs) for photocatalysis. In total, 76 conjugated polymers …
Semiconducting polymers for oxygen evolution reaction under light illumination
Y Fang, Y Hou, X Fu, X Wang - Chemical Reviews, 2022 - ACS Publications
Sunlight-driven water splitting to produce hydrogen fuel has stimulated intensive scientific
interest, as this technology has the potential to revolutionize fossil fuel-based energy …
interest, as this technology has the potential to revolutionize fossil fuel-based energy …