Concepts in the design and engineering of single-molecule electronic devices

N **n, J Guan, C Zhou, X Chen, C Gu, Y Li… - Nature Reviews …, 2019 - nature.com
Over the past two decades, various techniques for fabricating nano-gapped electrodes have
emerged, promoting rapid development in the field of single-molecule electronics, on both …

Emerging trends in spin crossover (SCO) based functional materials and devices

KS Kumar, M Ruben - Coordination Chemistry Reviews, 2017 - Elsevier
The design and synthesis of functional molecules with controllable properties are at the
forefront of modern materials chemistry research due to their diverse applicability, especially …

Electric-field mediated chemistry: uncovering and exploiting the potential of (oriented) electric fields to exert chemical catalysis and reaction control

S Shaik, D Danovich, J Joy, Z Wang… - Journal of the American …, 2020 - ACS Publications
This Perspective discusses oriented external-electric-fields (OEEF), and other electric-field
types, as “smart reagents”, which enable in principle control over wide-ranging aspects of …

Spin crossover nanomaterials: from fundamental concepts to devices

G Molnár, S Rat, L Salmon, W Nicolazzi… - Advanced …, 2018 - Wiley Online Library
Nanoscale spin crossover materials capable of undergoing reversible switching between
two electronic configurations with markedly different physical properties are excellent …

Structure and reactivity/selectivity control by oriented-external electric fields

S Shaik, R Ramanan, D Danovich… - Chemical Society …, 2018 - pubs.rsc.org
This is a tutorial on use of external-electric-fields (EEFs) as effectors of chemical change.
The tutorial instructs readers how to conceptualize and design electric-field effects on bonds …

Oriented electric fields as future smart reagents in chemistry

S Shaik, D Mandal, R Ramanan - Nature chemistry, 2016 - nature.com
Oriented external electric fields (OEEFs) as' smart reagents' are no longer a theoretical
dream. Here, we discuss the wide-ranging potential of using OEEFs to catalyse and control …

Molecular magnetism, quo vadis? A historical perspective from a coordination chemist viewpoint☆

J Ferrando-Soria, J Vallejo, M Castellano… - Coordination Chemistry …, 2017 - Elsevier
Molecular magnetism has travelled a long way from the pioneering studies on electron
exchange and double exchange or spin crossover and valence tautomerism in small …

Single-molecule junction: A reliable platform for monitoring molecular physical and chemical processes

X **e, P Li, Y Xu, L Zhou, Y Yan, L **e, C Jia, X Guo - ACS nano, 2022 - ACS Publications
Monitoring and manipulating the physical and chemical behavior of single molecules is an
important development direction of molecular electronics that aids in understanding the …

Electric field–induced selective catalysis of single-molecule reaction

X Huang, C Tang, J Li, LC Chen, J Zheng, P Zhang… - Science …, 2019 - science.org
Oriented external electric fields (OEEFs) offer a unique chance to tune catalytic selectivity by
orienting the alignment of the electric field along the axis of the activated bond for a specific …

External electric field effects on chemical structure and reactivity

T Stuyver, D Danovich, J Joy… - Wiley Interdisciplinary …, 2020 - Wiley Online Library
In recent years, external electric fields (EEFs) have captured some spotlight as novel
effectors of chemical change. EEFs directly impact the structure of molecular systems. For …