Acyclic diene metathesis polymerization: History, methods and applications

LC da Silva, G Rojas, MD Schulz… - Progress in Polymer …, 2017 - Elsevier
Abstract Acyclic Diene Metathesis (ADMET) polymerization was established decades ago
and has since developed into a robust and reliable technique. A wide range of different, new …

Precision polymers through ADMET polymerization

MD Schulz, KB Wagener - Macromolecular Chemistry and …, 2014 - Wiley Online Library
Acyclic diene metathesis (ADMET) polymerization is a unique strategy for achieving
polymers with precise control over the primary structure. This precision is obtained by …

Chemically recyclable linear and branched polyethylenes synthesized from stoichiometrically self-balanced telechelic polyethylenes

YJ Jang, S Nguyen, MA Hillmyer - Journal of the American …, 2024 - ACS Publications
High-density polyethylene (HDPE) is a widely used commercial plastic due to its excellent
mechanical properties, chemical resistance, and water vapor barrier properties. However …

Synthesis of bio-based aliphatic polyesters from plant oils by efficient molecular catalysis: A selected survey from recent reports

K Nomura, NW Binti Awang - ACS Sustainable Chemistry & …, 2021 - ACS Publications
Recent development in efficient synthesis of (unsaturated) 1, ω-fatty acid diesters (and the
diols), which can be used as monomers for synthesis of long chain aliphatic polyesters …

Simultaneous enhancement in processability and mechanical properties of polyethylenes via tuning the molecular weight distribution from unimodal to bimodal shape

C Long, Z Dong, X Liu, F Yu, Y Shang, K Wang, S Feng… - Polymer, 2022 - Elsevier
Semicrystalline polymers with bimodal molecular weight distribution (MWD) have captured
broad interest in academia and industry. Current efforts to understand the effect of bimodal …

Molecular weight distribution shape approach for simultaneously enhancing the stiffness, ductility and strength of isotropic semicrystalline polymers based on linear …

C Long, Z Dong, K Wang, F Yu, C He, ZR Chen - Polymer, 2023 - Elsevier
Bimodal polyethylenes (PEs) have captured broad attention in recent years, while little is
known about the contribution of bimodal molecular weight distribution (MWD) shape on their …

From polyethylene to polyester: influence of ester groups on the physical properties

MPF Pepels, MR Hansen, H Goossens… - …, 2013 - ACS Publications
Aliphatic long-chain polyesters (ALCPEs) were synthesized using the ring-opening
metathesis copolymerization of ambrettolide and cis-cyclooctene followed by exhaustive …

Direct all-atom molecular dynamics simulations of the effects of short chain branching on polyethylene oligomer crystal nucleation

W Zhang, RG Larson - Macromolecules, 2018 - ACS Publications
Using all-atom molecular dynamics (MD) simulations, we demonstrate that short alkyl
branches can hinder the nucleation of polyethylene (PE) oligomers. Although one methyl …

Molecular weight distribution shape dependence of the crystallization kinetics of semicrystalline polymers based on linear unimodal and bimodal polyethylenes

C Long, Z Dong, F Yu, K Wang, C He… - ACS Applied Polymer …, 2023 - ACS Publications
The manipulation of the crystallization kinetics and crystallinity of polymers without altering
their chemical composition, chain structure, or average molecular weight is challenging …

Precision vinyl acetate/ethylene (VAE) copolymers by ROMP of acetoxy-substituted cyclic alkenes

J Zhang, ME Matta, H Martinez, MA Hillmyer - Macromolecules, 2013 - ACS Publications
Precision linear vinyl acetate/ethylene (VAE) copolymers containing acetoxy groups on
precisely every eighth backbone carbon were synthesized by ring-opening metathesis …