Recent progress on exploring µ-oxo bridged binuclear porphyrinoid complexes in catalysis and material science

AB Sorokin - Coordination Chemistry Reviews, 2019 - Elsevier
This review covers recent advances in the preparation, characterization and application of µ-
oxo dimeric complexes with different metals and non-metal and macrocyclic ligands …

Noble Metal Porphyrin Complexes. Intermediates of Catalytic Processes (A Review)

EY Tyulyaeva - Russian Journal of Inorganic Chemistry, 2023 - Springer
A wide variety of oxidation states and coordination numbers of complexing cations, various
redox properties, high stability of the coordination center, as well as a unique electronic …

Oxygen atom transfer reactions from isolated (oxo) manganese (V) corroles to sulfides

A Kumar, I Goldberg, M Botoshansky… - Journal of the …, 2010 - ACS Publications
A series of five free-base corroles were metalated and brominated to form 10 manganese
(III) corroles. Two of the free-base corroles and six manganese (III) corroles were analyzed …

Cercosporin-bioinspired selective photooxidation reactions under mild conditions

J Li, W Bao, Z Tang, B Guo, S Zhang, H Liu… - Green …, 2019 - pubs.rsc.org
The development of an efficient system for selective oxidation of organic compounds to
generate more valuable compounds with molecular oxygen is a significant challenge in …

Selective aerobic oxidation of 5-hydroxymethylfurfural in water over solid ruthenium hydroxide catalysts with magnesium-based supports

YY Gorbanev, S Kegnæs, A Riisager - Catalysis letters, 2011 - Springer
Solid catalyst systems comprised of ruthenium hydroxide supported on magnesium-based
carrier materials (spinel, magnesium oxide and hydrotalcite) were investigated for the …

Catalyst- and Oxidizing Reagent-Free Electrochemical Benzylic C(sp3)–H Oxidation of Phenol Derivatives

ZW Hou, MM Zhang, WC Yang… - The Journal of Organic …, 2022 - ACS Publications
A site-selective electrochemical approach for the benzylic C (sp3)–H oxidation reaction of
phenol derivatives along with hydrogen evolution has been developed. The protocol …

Arylruthenium(III) Porphyrin-Catalyzed C–H Oxidation and Epoxidation at Room Temperature and [RuV(Por)(O)(Ph)] Intermediate by Spectroscopic Analysis and …

KP Shing, B Cao, Y Liu, HK Lee, MD Li… - Journal of the …, 2018 - ACS Publications
The development of highly active and selective metal catalysts for efficient oxidation of
hydrocarbons and identification of the reactive intermediates in the oxidation catalysis are …

Characteristics and reactivity of ruthenium–oxo complexes

T Ishizuka, H Kotani, T Kojima - Dalton Transactions, 2016 - pubs.rsc.org
In this perspective, we have surveyed the synthetic procedure, characteristics, and reactivity
of high-valent ruthenium–oxo complexes. The ruthenium–oxo complexes have served as …

Highly Active and Robust Ruthenium Complexes Based on Hemilability of Hybrid Ligands for C–H Oxidation

CB Bo, Q Bu, X Li, G Ma, D Wei, C Guo… - The Journal of Organic …, 2020 - ACS Publications
Evaluation of the hemilability of hybrid ligands provides a key to understand the metal–
ligand cooperation in transition metal catalysis. Here, we design and synthesize a type of …

Generation of an Isolable, Monomeric Manganese(V)–Oxo Complex from O2 and Visible Light

KA Prokop, DP Goldberg - Journal of the American Chemical …, 2012 - ACS Publications
The direct conversion of a MnIII complex [(TBP8Cz) MnIII (1)] to a MnV–oxo complex
[(TBP8Cz) MnV (O)(2)] with O2 and visible light is reported. Complex 1 is also shown to …