Recent advances in wave function-based methods of molecular-property calculations
Our understanding of the electronic structure of molecules often comes from spectroscopic
investigations in which electromagnetic radiation is applied to a molecule and the scattering …
investigations in which electromagnetic radiation is applied to a molecule and the scattering …
Acoustic gas thermometry
We review the principles, techniques and results from primary acoustic gas thermometry
(AGT). Since the establishment of ITS-90, the International Temperature Scale of 1990 …
(AGT). Since the establishment of ITS-90, the International Temperature Scale of 1990 …
Effects of adiabatic, relativistic, and quantum electrodynamics interactions on the pair potential and thermophysical properties of helium
The adiabatic, relativistic, and quantum electrodynamics (QED) contributions to the pair
potential of helium were computed, fitted separately, and applied, together with the …
potential of helium were computed, fitted separately, and applied, together with the …
Perspectives for a new realization of the pascal by optical methods
Since the beginning of measurement of pressure in the 17th century, the unit of pressure has
been defined by the relationship of force per unit area. The present state of optical …
been defined by the relationship of force per unit area. The present state of optical …
[HTML][HTML] Ab initio calculation of fluid properties for precision metrology
Recent advances regarding the interplay between ab initio calculations and metrology are
reviewed, with particular emphasis on gas-based techniques used for temperature and …
reviewed, with particular emphasis on gas-based techniques used for temperature and …
Ab initio pair potential energy curve for the argon atom pair and thermophysical properties for the dilute argon gas. II. Thermophysical properties for low-density argon
E Vogel, B Jäger, R Hellmann, E Bich - Molecular Physics, 2010 - Taylor & Francis
A recent argon–argon interatomic potential energy curve determined from quantum-
mechanical ab initio calculations and described with an analytical representation [B. Jäger …
mechanical ab initio calculations and described with an analytical representation [B. Jäger …
Polarizability of helium and gas metrology
Using a quasispherical, microwave cavity resonator, we measured the refractive index of
helium to deduce its molar polarizability A ε in the limit of zero density. We obtained (A ε …
helium to deduce its molar polarizability A ε in the limit of zero density. We obtained (A ε …
Theoretical determination of the polarizability dispersion and the refractive index of helium
The refractive index n of gaseous helium can be measured by optical interferometry so
accurately that it can be used to establish a pressure standard which is expected to be …
accurately that it can be used to establish a pressure standard which is expected to be …
Perspective on the refractive-index gas metrology data landscape
P Rourke - Journal of Physical and Chemical Reference Data, 2021 - pubs.aip.org
The redefinition of the kelvin has increased focus on thermometry techniques that use the
newly fixed value of the Boltzmann constant to realize thermodynamic temperature. One …
newly fixed value of the Boltzmann constant to realize thermodynamic temperature. One …
Refractive-index gas thermometry
PMC Rourke, C Gaiser, B Gao, DM Ripa… - Metrologia, 2019 - iopscience.iop.org
The principles and techniques of primary refractive-index gas thermometry (RIGT) are
reviewed. Absolute primary RIGT using microwave measurements of helium-filled quasi …
reviewed. Absolute primary RIGT using microwave measurements of helium-filled quasi …