Electro-optical π-radicals: design advances, applications and future perspectives

P Murto, H Bronstein - Journal of Materials Chemistry C, 2022 - pubs.rsc.org
The unique open-shell electronic structure of neutral π-radicals has inspired research on
novel molecular materials for over a century. In recent years, rapid development in carbon …

Chirality‐Induced Spin Selectivity: An Enabling Technology for Quantum Applications

A Chiesa, A Privitera, E Macaluso… - Advanced …, 2023 - Wiley Online Library
Molecular spins are promising building blocks of future quantum technologies thanks to the
unparalleled flexibility provided by chemistry, which allows the design of complex structures …

Excited‐State Dynamics of Non‐Luminescent and Luminescent π‐Radicals

Y Teki - Chemistry–A European Journal, 2020 - Wiley Online Library
Recently, the potential use of organic π‐radicals and related spin systems has been
expanded to modern technological applications. The unique excited‐state dynamics of …

Photogenerated spin-correlated radical pairs: From photosynthetic energy transduction to quantum information science

SM Harvey, MR Wasielewski - Journal of the American Chemical …, 2021 - ACS Publications
More than a half century ago, the NMR spectra of diamagnetic products resulting from
radical pair reactions were observed to have strongly enhanced absorptive and emissive …

Quantum gate operations on a spectrally addressable photogenerated molecular electron spin-qubit pair

H Mao, GJ Pazera, RM Young… - Journal of the …, 2023 - ACS Publications
Sub-nanosecond photodriven electron transfer from a molecular donor to an acceptor can
be used to generate a radical pair (RP) having two entangled electron spins in a well …

Open-shell organic semiconductors: an emerging class of materials with novel properties

Y Huang, E Egap - Polymer Journal, 2018 - nature.com
Organic materials with unpaired electrons along with the discovery of their unique properties
have fascinated scientists for over a century. The development of open-shell molecules has …

Photoinduced electron transfer and hole migration in nanosized helical aromatic oligoamide foldamers

X Li, N Markandeya, G Jonusauskas… - Journal of the …, 2016 - ACS Publications
A series of photoactive triads have been synthesized and investigated in order to elucidate
photoinduced electron transfer and hole migration mechanism across nanosized, rigid …

Photoinduced electron transfer from rylenediimide radical anions and dianions to Re (bpy)(CO) 3 using red and near-infrared light

NT La Porte, JF Martinez, S Hedström, B Rudshteyn… - Chemical …, 2017 - pubs.rsc.org
A major goal of artificial photosynthesis research is photosensitizing highly reducing metal
centers using as much as possible of the solar spectrum reaching Earth's surface. The …

Transient epr

S Weber - EPR Spectroscopy: Fundamentals and Methods, 2018 - books.google.com
Transient EPR (trEPR) spectroscopy is a time-resolved detection technique that has been
pioneered by Soon Sam Kim and Samuel I. Weissman in the late 1970s. 1, 2 It has proven to …

Covalent radical pairs as spin qubits: Influence of rapid electron motion between two equivalent sites on spin coherence

Y Wu, J Zhou, JN Nelson, RM Young… - Journal of the …, 2018 - ACS Publications
Ultrafast photodriven electron transfer reactions starting from an excited singlet state in an
organic donor–acceptor molecule generate a radical pair (RP) in which the two spins are …