The high utility of halogenated organic compounds has prompted the development of a vast
number of transformations which install the carbon–halogen motif. Traditional routes to …

Aliphatic azides are a versatile class of compounds found in a variety of biologically active
pharmaceuticals. These compounds are also recognized as useful precursors for the …

A regioselective synthesis of β-and γ-fluorinated ketones via silver-catalyzed ring opening is
described. A variety of β-and γ-fluorinated ketones are efficiently prepared, respectively …

The generation of azide radical (N3˙) occurs from its precursors primarily via a single
electron transfer (SET) process or homolytic cleavage by chemical methods or advanced …

Substitution by the CF3S group allows for an increase in lipophilicity and electron-
withdrawing properties along with an improvement in the bioavailability of medicinal targets; …

An efficient Mn-catalyzed aerobic oxidative hydroxyazidation of olefins for synthesis of β-
azido alcohols has been developed. The aerobic oxidative generation of azido radical …

Asymmetric copper‐catalyzed intermolecular amino‐and azidocyanation reactions of
alkenes have been developed that proceed via a radical process in which a key benzylic …

The azido group is found in large numbers of natural products, drugs, biochemicals and
materials and to date, many elegant and useful methods for the synthesis of organic azides …

The installation of trifluoromethyl groups has become an essential step across a number of
industries such as agrochemicals, drug discovery, and materials. Consequently, the rapid …

We report herein an efficient and general method for the decarboxylative azidation of
aliphatic carboxylic acids. Thus, with AgNO3 as the catalyst and K2S2O8 as the oxidant, the …