Computational studies on thermo-kinetics aspects of pyrolysis of isopropyl acetate and its methyl, bromide and hydroxyl derivatives

SHR Shojaei, A Shiroudi, MA Abdel-Rahman - Heliyon, 2022 - cell.com
The gas-phase decomposition kinetics of isopropyl acetate (IPA) and its methyl, bromide
and hydroxyl derivatives into the corresponding acid and propene were investigated using …

Theoretical study of the oxidation mechanisms of naphthalene initiated by hydroxyl radicals: the O 2 addition reaction pathways

A Shiroudi, MS Deleuze, S Canneaux - Physical Chemistry Chemical …, 2015 - pubs.rsc.org
Atmospheric oxidation of the naphthalene–OH adduct [C10H8OH]˙(R1) by molecular
oxygen in its triplet electronic ground state has been studied using density functional theory …

Theoretical study of the oxidation mechanisms of naphthalene initiated by hydroxyl radicals: the H abstraction pathway

A Shiroudi, MS Deleuze - The Journal of Physical Chemistry A, 2014 - ACS Publications
Reaction mechanisms for the initial stages of naphthalene oxidation at high temperatures
(T≥ 600 K) have been studied theoretically using density functional theory along with …

Theoretical study on the mechanisms and kinetics of the β-elimination of 2, 2-dihaloethyltrihalosilanes (X= F, Cl, Br) compounds: a DFT study along with a natural …

AR Oliaey, A Shiroudi, E Zahedi… - … Kinetics, Mechanisms and …, 2018 - Springer
The β-elimination kinetics of 2, 2-dihaloethyltrihalosilanes in the gas phase has been
studied computationally using density functional theory (DFT) along with the M06-2 x …

Unveiling the structure‐reactivity relationship involved in the reaction mechanism of the HCl‐catalyzed alkyl t‐butyl ethers thermal decomposition. A computational …

SA Cuesta, JR Mora, LM Meneses… - … Journal of Quantum …, 2022 - Wiley Online Library
The gas‐phase thermal decomposition of a series of alkyl t‐butyl ethers catalyzed by
hydrogen chloride is theoretically studied at the ωB97XD/6‐311++ g (d)//CCSD (T)/6‐311++ …

Reaction mechanisms and kinetics of the isomerization processes of naphthalene peroxy radicals

A Shiroudi, MS Deleuze - Computational and Theoretical Chemistry, 2015 - Elsevier
The isomerization processes of naphthalene peroxy radicals [C 10 H 8–OH] radical dot–O 2
into bicyclic peroxy or oxy hydroperoxide radicals via ring closure and intramolecular …

Kinetics and mechanisms of the thermal decomposition of 2-methyl-1, 3-dioxolane, 2, 2-dimethyl-1, 3-dioxolane, and cyclopentanone ethylene ketal in the gas phase …

F Rosas, J Lezama, JR Mora… - The Journal of …, 2012 - ACS Publications
The kinetics of the gas-phase thermal decomposition of 2-methyl-1, 3-dioxolane, 2, 2-
dimethyl-1, 3-dioxolane, and cyclopentanone ethylene ketal were determined in a static …

[HTML][HTML] Reaction mechanisms and kinetics of the β-elimination processes of compounds CHF2CH2SiFnMe3–n (n= 0–3): DFT and CBS-QB3 methods using Rice …

Z Safaei, A Shiroudi, R Padash, M Sillanpää… - Journal of Fluorine …, 2018 - Elsevier
The gas-phase β-elimination kinetics of 2, 2-difluoroethyltrifluorosilane (1), 2, 2-
difluoroethylmethyldifluorosilane (2), 2, 2-difluoroethyldimethylfluorosilane (3), and 2, 2 …

Theoretical study on the elimination kinetics in the gas phase of allyl methyl compounds

AR Oliaey, A Shiroudi, E Zahedi… - Monatshefte für Chemie …, 2018 - Springer
The thermal decomposition kinetics of allyl methyl amine, allyl methyl ether, and allyl methyl
sulfide in the gas phase has been studied theoretically using the M06-2 x/aug-cc-pVTZ …

Electrocyclic [1,5] hydrogen shift in the thermal elimination kinetics of phenyl acetate and p-tolyl acetate in the gas phase: a density functional theory study

E Marquez, A Maldonado, F Rosas, B Ramirez… - Molecular …, 2014 - Taylor & Francis
The kinetics and mechanisms of thermal decomposition of phenyl acetate and p-tolyl acetate
in the gas phase were studied by means of electronic structure calculations using density …