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Recent advances in the isolation and reactivity of organogold complexes
LP Liu, GB Hammond - Chemical Society Reviews, 2012 - pubs.rsc.org
Homogeneous gold catalysis has been one of the most active research fields in organic
chemistry for more than a decade, and it has been also among the most efficient …
chemistry for more than a decade, and it has been also among the most efficient …
Ag–NHC Complexes in the π-Activation of Alkynes
Silver–NHC (NHC= N-heterocyclic carbene) complexes play a special role in the field of
transition-metal complexes due to (1) their prominent biological activity, and (2) their critical …
transition-metal complexes due to (1) their prominent biological activity, and (2) their critical …
Ligand effects and ligand design in homogeneous gold (I) catalysis
W Wang, GB Hammond, B Xu - Journal of the American Chemical …, 2012 - ACS Publications
Gold catalysis is considered one of the most important breakthroughs in organic synthesis
during the past decade, but a rational understanding of ligand effects in gold catalysis is …
during the past decade, but a rational understanding of ligand effects in gold catalysis is …
Hexafluoroisopropanol (HFIP) as a multifunctional agent in gold-catalyzed cycloisomerizations and sequential transformations
Despite the unique position of gold catalysis in contemporary organic synthesis, this area of
research is notorious for requiring activators and/or additives that enable catalysis by …
research is notorious for requiring activators and/or additives that enable catalysis by …
Divergent synthesis of carbo-and heterocycles via gold-catalyzed reactions
Y Wei, M Shi - ACS Catalysis, 2016 - ACS Publications
The latest advances in the field of gold-catalyzed divergent synthesis of carbo-and
heterocycles are highlighted in this Perspective. These gold-catalyzed reactions, which can …
heterocycles are highlighted in this Perspective. These gold-catalyzed reactions, which can …
Hydrogen bonding-enabled gold catalysis: ligand effects in gold-catalyzed cycloisomerizations in hexafluoroisopropanol (HFIP)
Gold catalysis has witnessed immense evolution in recent years, yet it still requires the use
of activators to render the common [AuCl (L)] complexes catalytically active. Herein, the H …
of activators to render the common [AuCl (L)] complexes catalytically active. Herein, the H …
Enantioselective gold-catalyzed synthesis of polycyclic indolines
The synthesis of architecturally complex polycyclic fused indolines is achieved in a chemo-,
regio-, and stereodefined manner, via an enantioselective gold-catalyzed cascade …
regio-, and stereodefined manner, via an enantioselective gold-catalyzed cascade …
On homogeneous gold/palladium catalytic systems
ASK Hashmi, C Lothschütz, R Döpp… - Advanced Synthesis …, 2012 - Wiley Online Library
Two substrates containing an aryl iodide and an allenoate ester were prepared and the gold‐
induced cycloisomerisation to vinylgold (I) species and their proto‐deauration as well as the …
induced cycloisomerisation to vinylgold (I) species and their proto‐deauration as well as the …
Mechanistic analysis of gold (I)-catalyzed intramolecular allene hydroalkoxylation reveals an off-cycle bis (gold) vinyl species and reversible C–O bond formation
TJ Brown, D Weber, MR Gagné… - Journal of the American …, 2012 - ACS Publications
Mechanistic investigation of gold (I)-catalyzed intramolecular allene hydroalkoxylation
established a mechanism involving rapid and reversible C–O bond formation followed by …
established a mechanism involving rapid and reversible C–O bond formation followed by …
NHC–Gold (I) complexes as effective catalysts for the carboxylative cyclization of propargylamines with carbon dioxide
S Hase, Y Kayaki, T Ikariya - Organometallics, 2013 - ACS Publications
NHC–gold (I) complexes promote carboxylative cyclization of a range of propargylic amines
to afford (Z)-5-alkylidene-1, 3-oxazolidin-2-ones in methanol under neutral and mild …
to afford (Z)-5-alkylidene-1, 3-oxazolidin-2-ones in methanol under neutral and mild …