The employment of weak intermolecular interactions in supramolecular chemistry offers an
alternative approach to project artificial chemical environments like the active sites of …

The continued development of molecular architectures of consequence to both longstanding
and newly recognized problems demands ever evolving synthetic routes, characterizations …

Although metallosupramolecular cages are self-assembled from seemingly simple building
blocks, metal ions and organic ligands, architectures of increasingly large size and …

Conspectus Coordination-driven self-assembly can produce large, symmetrical, hollow
cages that are synthetically easy to access. The functions provided by these aesthetically …

Since as early as 1867, molecular sensors have been recognized as being intelligent
“devices” capable of addressing a variety of issues related to our environment and health …

Transition metal catalysis plays an important role in both industry and in academia where
selectivity, activity and stability are crucial parameters to control. Next to changing the …

During the past few decades, great efforts have been devoted to the design and self-
assembly of discrete metal–organic cages/containers (MOCs) with increasing complexity …

A Tutorial Review of the subtle supramolecular interactions influencing the outcomes of
equilibrating systems, focusing on the dynamic covalent chemistry (DCC) of disulfide …

Conspectus As Pasteur noted more than 150 years ago, asymmetry exists in matter at all
organization levels. Biopolymers such as proteins or DNA adopt one-handed conformations …

Gels formed via metal–ligand coordination typically have very low branch functionality, f, as
they consist of∼ 2–3 polymer chains linked to single metal ions that serve as junctions …