50 years ago, Karl Ziegler and Giulio Natta were awarded the Nobel Prize for their discovery
of the catalytic polymerization of ethylene and propylene using titanium compounds and …

Abstract Since 1963, when Karl Ziegler and Giulio Natta were jointly awarded the Nobel
Prize for their discoveries of the catalytic polymerization of olefins with Ti-chlorides and Al …

Since polypropylene was synthesized in 1954, tremendous breakthroughs have been
achieved in transferring polypropylene from a discovery in the laboratory to an …

In this study, magnetic multi-walled carbon nanotubes were functionalized with
polyamidoamine (PAMAM) dendrimers and modified with butylsulfonate to afford …

The role of the pore architecture of the Ziegler-Natta (ZN) catalysts in the propylene
polymerizations is unveiled, towards the catalyst activity, H 2–and comonomer-response …

MgCl2 supported Ziegler–Natta (Z–N) catalysts have emerged as the most exciting chemical
process for polyolefin technology, which is responsible for the production of∼ 150 million …

This study undertakes a thorough computational exploration of Ziegler–Natta catalysis,
emphasizing the role of external donors, particularly dicyclopentyldimethoxysilane (D …

This article studies the effects of arsine on the synthesis and thermal degradation of 4
samples of virgin polypropylene (PP-virgin) and proposes reaction mechanisms that allow …

In this article, the pyrolysis and thermo-degradation of 11 virgin-polypropylene (virgin-PP)
with different levels of arsenic in its polymer matrix, was carried out in a discontinuous quartz …

This work conducts an investigation into how the polymerization conditions affect the kinetics
of ethylene homopolymerization and the properties of the final polyethylene using a …