The chemistry of α-haloketones and their utility in heterocyclic synthesis

AW Erian, SM Sherif, HM Gaber - Molecules, 2003 - mdpi.com
Molecules | Free Full-Text | The Chemistry of α-Haloketones and Their Utility in Heterocyclic
Synthesis Next Article in Journal Synthesis and Crystal Structure of Hexakis(imidazole) nickel …

Recent developments in the Birch reduction of aromatic compounds: applications to the synthesis of natural products

JM Hook, LN Mander - Natural Product Reports, 1986 - pubs.rsc.org
Recent Developments in the Birch Reduction of Aromatic Compounds: Applications to the
Synthesis of Natural Products Page 1 Recent Developments in the Birch Reduction of Aromatic …

[LIBRO][B] Tandem organic reactions

TL Ho - 1992 - books.google.com
The importance of tandem reactions is evident--besides their pragmatic value, they have an
aesthetic appeal. The author presents a survey of these reactions that will rivet the attention …

Three‐Component Reaction of Pentafluorosulfanyl Chloride, Alkenes and Diazo Compounds and Synthesis of Pentafluorosulfanylfurans

JY Shou, FL Qing - Angewandte Chemie International Edition, 2022 - Wiley Online Library
We report herein the three‐component radical addition reaction of SF5Cl, alkene and diazo
compounds for the selective formation of α‐alkyl‐α‐SF5 carbonyl compounds. The three …

Electrocatalytic [3+ 2] Annulation for the Synthesis of Polysubstituted Furans

M Chen, J Wang, Y Kan, X Jia, B Huang, T Li… - Organic …, 2023 - ACS Publications
In this report we describe an atom-economic, practical strategy for the synthesis of tri/tetra-
substituted furans through electrochemical [3+ 2] annulation between alkynes and β-keto …

The use of silyl ketene acetals and enol ethers in the catalytic enantioselective alkylative ring opening of oxa/aza bicyclic alkenes

L Zhang, CM Le, M Lautens - … Chemie International Edition, 2014 - Wiley Online Library
Silyl ketene acetals and enol ethers are employed as reactive and functional group tolerant
nucleophiles in the enantioselective rhodium‐catalyzed alkylative ring opening of a diverse …

Macroexpansion methodology: Medium ring synthesis based on an eight unit ring expansion process

PA Wender, SMN Sieburth, JJ Petraitis, SK Singh - Tetrahedron, 1981 - Elsevier
Treatment of 1, 2-(E, E)-di (1-buta-1, 3-dienyl) cyclohexanol (21) with potassium hydride in
tetrahydrofuran at room temperature resulted in the facile formation of a 14-membered ring …

The synthesis of germacrane sesquiterpenes and related compounds

AJ Minnaard, JBPA Wijnberg, A de Groot - Tetrahedron, 1999 - Elsevier
The synthesis of germacrane sesquiterpenes and related compounds - ScienceDirect Skip to
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Silicon in synthesis—17: Chloromethyl (trimethylsilyl) lithium—anew reagent for the direct conversion of aldehydes and ketones into⇌, β,-epoxytrimethylsilanes

C Burford, F Cooke, G Roy, P Magnus - Tetrahedron, 1983 - Elsevier
Treatment of chloromethyltrimethylsilane 1 with sec-BuLi in THF at-78° produces
chloromethyl (tri-methylsilyl) lithium 4. Treatment of 4 with a wide range of aldehydes and …

Ab initio analysis of the Cope rearrangement of germacrane sesquiterpenoids

WN Setzer - Journal of Molecular Modeling, 2008 - Springer
The energetics of the Cope rearrangement of 17 germacrane sesquiterpenoids to their
respective elemane forms have been calculated using both density functional theory …