Emerging trends in spin crossover (SCO) based functional materials and devices

KS Kumar, M Ruben - Coordination Chemistry Reviews, 2017 - Elsevier
The design and synthesis of functional molecules with controllable properties are at the
forefront of modern materials chemistry research due to their diverse applicability, especially …

Vapochromic effect in switchable molecular-based spin crossover compounds

E Resines-Urien, E Fernandez-Bartolome… - Chemical Society …, 2023 - pubs.rsc.org
Coordination complexes based on transition metal ions displaying [Ar] 3d4–3d7 electronic
configurations can undergo the likely most spectacular switchable phenomena found in …

Spin-crossover iron (II) coordination polymer with fluorescent properties: Correlation between emission properties and spin state

C Lochenie, K Schötz, F Panzer, H Kurz… - Journal of the …, 2018 - ACS Publications
A spin-crossover coordination polymer [Fe (L1)(bipy)] n (where L= a N2O22–coordinating
Schiff base-like ligand bearing a phenazine fluorophore and bipy= 4, 4′-bipyridine) was …

Non‐Porous Iron (II)‐Based Sensor: Crystallographic Insights into a Cycle of Colorful Guest‐Induced Topotactic Transformations

S Rodríguez‐Jiménez, HLC Feltham… - Angewandte Chemie …, 2016 - Wiley Online Library
Materials capable of sensing volatile guests at room temperature by an easily monitored set
of outputs are of great appeal for development as chemical sensors of small volatile …

Reversible quantitative guest sensing via spin crossover of an iron (II) triazole

RG Miller, S Brooker - Chemical Science, 2016 - pubs.rsc.org
A new phenyl-triazole-pyrazine ligand, 4-p-tolyl-3-(phenyl)-5-(2-pyrazinyl)-1, 2, 4-triazole
(tolpzph), was prepared in order to enforce pyrazine coordination of the iron (II) centre in the …

Correlations between ligand field Δ o, spin crossover T 1/2 and redox potential E pa in a family of five dinuclear helicates

S Singh, S Brooker - Chemical Science, 2021 - pubs.rsc.org
A family of five new bis-bidentate azole–triazole Rat ligands (1, 3-bis (5-(azole)-4-isobutyl-
4H-1, 2, 4-triazol-3-yl) benzene), varying in choice of azole (2-imidazole, 4-imidazole, 1 …

Spin Crossover in Fe(II) Complexes with N4S2 Coordination

A Arroyave, A Lennartson… - Inorganic …, 2016 - ACS Publications
Reactions of Fe (II) precursors with the tetradentate ligand S, S′-bis (2-pyridylmethyl)-1, 2-
thioethane (bpte) and monodentate NCE–coligands afforded mononuclear complexes [Fe …

Three-way switchable single-crystal-to-single-crystal solvatomorphic spin crossover in a molecular cocrystal

AR Zuluaga, AJ Brock, MC Pfrunder… - Chemistry of …, 2020 - ACS Publications
The Fe (III) spin-switching complexes [Fe (qsal-5-Y) 2] X (where Y= F, Cl, Br, I or OMe; X=
NCS–, Cl–, OTf–, NO3–, BF4–, PF6–, or BPh4–) display a variety of thermal spin transition …

Spin Crossover in Dinuclear N4S2 Iron(II) Thioether–Triazole Complexes: Access to [HS-HS], [HS-LS], and [LS-LS] States

RW Hogue, HLC Feltham, RG Miller… - Inorganic …, 2016 - ACS Publications
Access to a new family of thioether-linked PSRT ligands, 4-substituted-3, 5-bis {[(2-
pyridylmethyl) sulfanyl] methyl}-4 H-1, 2, 4-triazoles (analogues of the previously studied …

Different Spin‐State Behaviors in Isostructural Solvates of a Molecular Iron (II) Complex

LJK Cook, R Kulmaczewski… - … A European Journal, 2016 - Wiley Online Library
Abstract The complex [FeL2][BF4] 2 (1; L= 4‐(isopropylsulfanyl)‐2, 6‐di (pyrazol‐1‐yl)
pyridine) forms solvate crystals 1⋅ solv (solv= MeNO2, MeCN, EtCN, or Me2CO). Most of …