The structure, property, and ion irradiation effects of pyrochlores: a comprehensive review

Y Wang, C **g, ZY Ding, YZ Zhang, T Wei, JH Ouyang… - Crystals, 2023 - mdpi.com
Since the beginning of the use of nuclear energy, humans have been faced with the problem
of radionuclide disposal. At present, a large amount of waste is stored in pools or dry tanks …

Perspectives on pyrochlores, defect fluorites, and related compounds: building blocks for chemical diversity and functionality

GR Lumpkin, RD Aughterson - Frontiers in Chemistry, 2021 - frontiersin.org
In this article we provide some perspectives on a range of pyrochlore and defect fluorite type
compounds with nominal A2B2O7, A2BO5, ABC2O7, and other stoichiometries. Typically …

[HTML][HTML] Pyrochlore-type lanthanide titanates and zirconates: Synthesis, structural peculiarities, and properties

AF Fuentes, EC O'Quinn, SM Montemayor… - Applied Physics …, 2024 - pubs.aip.org
This contribution provides a thorough examination of the structural characteristics of
pyrochlore-type lanthanide titanates and zirconates Ln 2 Ti 2 O 7 and Ln 2 Zr 2 O 7, across …

Response of structure and mechanical properties of high entropy pyrochlore to heavy ion irradiation

L Xu, M Niu, H Wang, L Su, H Gao, L Zhuang - Journal of the European …, 2022 - Elsevier
Material with superior damage tolerance, chemical durability, and structure stability is of
increasing interest in high-level radioactive waste management and structural components …

Irradiation induced structural damage and evolution of mechanical properties in high entropy fluorite oxide

L Xu, L Su, M Niu, H Gao, K Peng, L Zhuang… - Journal of the European …, 2023 - Elsevier
Pursuing material with excellent irradiation resistance, high chemical durability, and stable
mechanical properties under extreme conditions is of great significance for develo** …

Defect formation energies in A2B2O7 pyrochlores

Y Li, PM Kowalski, G Beridze, AR Birnie, S Finkeldei… - Scripta Materialia, 2015 - Elsevier
We performed ab initio calculations of the cation antisite and anion Frenkel pair defect
formation energies for a series of pyrochlores. The obtained energies correlate well with the …

Investigation of local structure and phase recovery in an irradiated Nd 2 Zr 2 O 7 pyrochlore

Y Singh, SK Sharma, V Kumar, P Rajput… - Journal of Materials …, 2024 - pubs.rsc.org
The ordering and disordering processes significantly impact the physicochemical properties
of complex oxides when they are subjected to severe conditions such as high temperature …

Opposite correlations between cation disordering and amorphization resistance in spinels versus pyrochlores

BP Uberuaga, M Tang, C Jiang, JA Valdez… - Nature …, 2015 - nature.com
Understanding and predicting radiation damage evolution in complex materials is crucial for
develo** next-generation nuclear energy sources. Here, using a combination of ion beam …

Probing the short-range ordering of ion irradiated Gd2Ti2-yZryO7 (0.0≤ y≤ 2.0) pyrochlore under electronic stop** regime

A Kumar, SK Sharma, V Grover, Y Singh… - Journal of Nuclear …, 2022 - Elsevier
A series of Gd 2 Ti 2-y Zr y O 7 (0.0≤ y≤ 2.0) solid solutions has been synthesized by a
solid-state process using a three-stage heating protocol. Raman spectroscopy was used to …

Probing the temperature effects in the radiation stability of Nd2Zr2O7 pyrochlore under swift ion irradiation

SK Sharma, V Grover, AK Tyagi, DK Avasthi, UB Singh… - Materialia, 2019 - Elsevier
The pyrochlore structure is of particular interest to the nuclear industry due to its potential for
nuclear waste immobilization and as a host material for inert matrix fuels. Herein, the …