Transition-metal catalyzed reactions that are able to construct complex aliphatic amines from
simple, readily available feedstocks have become a cornerstone of modern synthetic …

Organometallic chemistry is generally considered the key to homogeneous catalysis, which,
although a century old, is still today a very dynamic discipline. 1 The past decade has seen …

Gold(I)-Catalyzed Intra- and Intermolecular Hydroamination of Unactivated Olefins | Journal
of the American Chemical Society ACS ACS Publications C&EN CAS Find my institution Log …

Asymmetric hydroamination allows the direct and selective formation of a new C N bond as
a simple procedure towards valuable scalemic synthons. Huge efforts have recently been …

The β-diketiminate-stabilized calcium amide complex [{ArNC (Me) CHC (Me) NAr} Ca {N
(SiMe3) 2}(THF)](Ar= 2, 6-diisopropylphenyl) and magnesium methyl complex [{ArNC (Me) …

The present review is focused on the application of computational/theoretical methods to the
wide and rich chemistry of allenes. Special emphasis is made on the interplay and synergy …

Tetrahydrobenzo [b] azepines (THBAs) are commonly found in many bioactive compounds;
however, the modular preparation of functionalized THBAs remains challenging to date …

Intermolecular addition of phenols, carboxylic acids, and protected amines to inert olefins
can be catalyzed by low concentrations (1− 5%) of triflic acid. Functional groups, such as the …

The heavier group 2 complexes [M {N (SiMe3) 2} 2] 2 (1, M= Ca; 2, M= Sr) and [M {CH
(SiMe3) 2} 2 (THF) 2](3, M= Ca; 4, M= Sr) are shown to be effective precatalysts for the …

This Perspective article provides an overview of the recent advancements in the field of intra-
and inter-molecular C–N, C–O and C–P bond formation by hydroamination …