Recent development in catalytic application of transition metal complexes having an M–E
bond (E= main group metal or metalloid element), which is stabilized by a multidentate …

This third review in a series involving reactions of hydrosilanes and transition metal
complexes and characterization of the products covers the period 2009 thru 2013. After a …

Provides a unique summary of important catalytic reactions in the presence of silicon A must-
have for all synthetic chemists, this book summarizes all of the important developments in …

The past decade has witnessed staggering progress in the chemistry of compounds with low‐
valent main‐group elements. Although these discoveries are mostly fundamental by nature …

A significant number of isolable silylenes are currently known. They have quickly developed
from laboratory curiosities to useful ligands in metal‐mediated homogeneous catalysis. This …

The transition-metal (TM) chemistry of heavier tetrylenes (HTs), also known as heavier
carbene analogs, group 14 metalenes or group 14 metalylenes (compounds containing Si …

Since the late 19th century, heavier tetrylene-and tetrylyne-transition metal chemistry has
formed an important cornerstone in both main-group and organometallic chemistry alike …

The nickel-catalyzed direct borylation and silylation of phenolic esters has been established.
The key to this highly efficient acyl C–O bond borylative and silylative cleavage depends on …

The synthesis and structure of the first 1, 2‐bis (NHSi)‐substituted ortho‐carborane [(LSi:) C]
2B10H10 (termed SiCCSi) is reported (NHSi= N‐heterocyclic silylene; L= PhC (NtBu) 2). Its …

The present account is a review of all N-heterocyclic silylene (NHSi) transition metal
complexes that have been employed in catalytic transformations, reported up to the present …