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Spiers Memorial Lecture: Mechanochemistry, tribochemistry, mechanical alloying–retrospect, achievements and challenges
E Boldyreva - Faraday Discussions, 2023 - pubs.rsc.org
Spiers Memorial Lecture: Mechanochemistry, tribochemistry, mechanical alloying –
retrospect, achievements and challenges - Faraday Discussions (RSC Publishing) DOI:10.1039/D2FD00149G …
retrospect, achievements and challenges - Faraday Discussions (RSC Publishing) DOI:10.1039/D2FD00149G …
Acceleration of Diels-Alder reactions by mechanical distortion
Challenges in quantifying how force affects bond formation have hindered the widespread
adoption of mechanochemistry. We used parallel tip-based methods to determine reaction …
adoption of mechanochemistry. We used parallel tip-based methods to determine reaction …
Mechanochemistry for Organic and Inorganic Synthesis
In recent years, mechanochemistry has become an innovative and sustainable alternative to
traditional solvent-based synthesis. Mechanochemistry rapidly expanded across a wide …
traditional solvent-based synthesis. Mechanochemistry rapidly expanded across a wide …
The regioselective solid‐state photo‐mechanochemical synthesis of nanographenes with UV light
Photochemical reactors inherently suffer from the low penetration depth of light and
therefore rely on high dilutions to enable chemical reactions. Here we present the first …
therefore rely on high dilutions to enable chemical reactions. Here we present the first …
Mechanophotocatalysis: A Generalizable Approach to Solvent‐minimized Photocatalytic Reactions for Organic Synthesis
F Millward, E Zysman‐Colman - … Chemie International Edition, 2024 - Wiley Online Library
This proof‐of‐concept study cements the viability and generality of mechanophotocatalysis,
merging mechanochemistry and photocatalysis to enable solvent‐minimized photocatalytic …
merging mechanochemistry and photocatalysis to enable solvent‐minimized photocatalytic …
Kinetics of primary mechanochemical covalent-bond-forming reactions
Mechanical activation of reactions can reduce significantly the amounts of solvent and
energy required to form covalent organic bonds. Despite growing interest in the field of …
energy required to form covalent organic bonds. Despite growing interest in the field of …
Mechano-photoexcitation for organic synthesis using mechanoluminescent materials as photon sources
X **n, J Geng, D Zhang, HT Ang, H Wang, Y Cheng… - Nature …, 2024 - nature.com
Implementing photochemical reactions through mechanochemical methods can reduce
waste generation by eliminating the need for bulk solvents. The absence of solvent results in …
waste generation by eliminating the need for bulk solvents. The absence of solvent results in …
Two-legged molecular walker and curvature: mechanochemical ring migration on graphene
Attaining controllable molecular motion at the nanoscale can be beneficial for multiple
reasons, spanning from optoelectronics to catalysis. Here we study the movement of a two …
reasons, spanning from optoelectronics to catalysis. Here we study the movement of a two …
Template-Directed In Crystallo Photopolymerization of a Donor–Acceptor Cyclopropane: When Everything Falls into Place!
M Giorgi, K Masson, S Chentouf… - Journal of the …, 2024 - ACS Publications
A single-crystal-to-single-crystal solid-state reaction of vinylogous donor–acceptor
cyclopropanes is documented. The enantiospecific synthesis of new products, distinct from …
cyclopropanes is documented. The enantiospecific synthesis of new products, distinct from …
Real‐Time In Situ Raman Monitoring of Photomechanochemical Reactions
In its ongoing development, mechanochemistry is becoming equipped with additional
energy inputs such as light. In this work we demonstrate a proof‐of‐principle setup for real …
energy inputs such as light. In this work we demonstrate a proof‐of‐principle setup for real …