This review surveys recent progress in the chemistry of polycyclic heteroaromatic molecules
with a focus on structural diversity and synthetic methodology. The article covers literature …

The replacement of one or more pyrrolic building block (s) of a porphyrin by a nonpyrrolic
heterocycle leads to the formation of so-called pyrrole-modified porphyrins (PMPs) …

Organocopper (III) species were generally considered as the key intermediates in a variety
of copper-catalyzed cross-coupling reactions, aerobic oxidations, as well as enzyme …

This Review outlines the progress in the field of synthetic expanded carbaporphyrinoids.
The evolution of this topic is demonstrated with expanded porphyrin‐inspired systems with a …

The analogue of octaphyrin (1.1. 1.0. 1.1. 1.0) bearing two dimethoxyphenanthrene units
was synthesized and characterized in solution and solid state. The macrocycle was …

Carbaporphyrin dimers, investigated for their distinctive electronic structures and
exceptional properties, have predominantly consisted of systems containing identical …

Controlling the aromaticity in expanded porphyrins is a forefront research topic, and the
strategy of using protonation-triggered conformational changes to fine-tune electronic …

Porphyrinoids in which one or two pyrrole rings are replaced with polycyclic aromatic
hydrocarbons/heterocycles such as naphthalene, phenanthrene, biphenyl, bipyridine, or …

Abstract Di‐2, 7‐naphthihexaphyrin (1.1. 1.1. 1.1), a non‐aromatic carba‐analogue of the
hexaphyrin (1.1. 1.1. 1.1), incorporating two built‐in 2, 7‐naphthylene moieties was …

This Review discusses the recent developments in the field of synthetic chemistry of PAH–
porphyrin hybrids, emphasizing phenanthrene‐embedded carbaporphyrinoids and related …