Emerging Trends in Cross-Coupling: Twelve-Electron-Based L1Pd(0) Catalysts, Their Mechanism of Action, and Selected Applications

SJ Firsan, V Sivakumar, TJ Colacot - Chemical Reviews, 2022 - ACS Publications
Monoligated palladium (0) species, L1Pd (0), have emerged as the most active catalytic
species in the cross-coupling cycle. Today, there are methods available to generate the …

Understanding active species in catalytic transformations: From molecular catalysis to nanoparticles, leaching,“Cocktails” of catalysts and dynamic systems

DB Eremin, VP Ananikov - Coordination Chemistry Reviews, 2017 - Elsevier
In the present review, we consider the transformations of molecular catalysts, leaching,
aggregation and various interconversions of metal complexes, clusters and nanoparticles …

Transition metal-catalysed molecular n-do** of organic semiconductors

H Guo, CY Yang, X Zhang, A Motta, K Feng, Y ** is a key process for investigating charge transport in organic
semiconductors and improving certain (opto) electronic devices,,,,,,,–. N (electron)-do** is …

Highly stretchable polymer semiconductor films through the nanoconfinement effect

J Xu, S Wang, GJN Wang, C Zhu, S Luo, L **, X Gu… - Science, 2017 - science.org
Soft and conformable wearable electronics require stretchable semiconductors, but existing
ones typically sacrifice charge transport mobility to achieve stretchability. We explore a …

[BOOK][B] The organometallic chemistry of the transition metals

RH Crabtree - 2009 - books.google.com
" One impressive and compressive book.... This review would have to be book size to do full
justice to all the insights in this volume."—Journal of Metals Online Fully updated and …

Univariate classification of phosphine ligation state and reactivity in cross-coupling catalysis

SH Newman-Stonebraker, SR Smith, JE Borowski… - Science, 2021 - science.org
Chemists often use statistical analysis of reaction data with molecular descriptors to identify
structure-reactivity relationships, which can enable prediction and mechanistic …

Key Green Chemistry research areas from a pharmaceutical manufacturers' perspective revisited

MC Bryan, PJ Dunn, D Entwistle, F Gallou… - Green …, 2018 - pubs.rsc.org
In 2007 the members of the ACS Green Chemistry Institute® Pharmaceutical Roundtable
assembled a list of key green chemistry research areas to both identify transformations that …

A design strategy for high mobility stretchable polymer semiconductors

J Mun, Y Ochiai, W Wang, Y Zheng, YQ Zheng… - Nature …, 2021 - nature.com
As a key component in stretchable electronics, semiconducting polymers have been widely
studied. However, it remains challenging to achieve stretchable semiconducting polymers …

Design and preparation of new palladium precatalysts for C–C and C–N cross-coupling reactions

NC Bruno, MT Tudge, SL Buchwald - Chemical science, 2013 - pubs.rsc.org
A series of easily prepared, phosphine-ligated palladium precatalysts based on the 2-
aminobiphenyl scaffold have been prepared. The role of the precatalyst-associated labile …

Metal-mediated and metal-catalyzed reactions of isocyanides

VP Boyarskiy, NA Bokach, KV Luzyanin… - Chemical …, 2015 - ACS Publications
1. INTRODUCTION A timely subtitle to this Review focused on conversions of isocyanides at
metal centers could have been “a platinum jubilee of the first metal-mediated reaction …