Transition metal-catalysed carbene-and nitrene transfer to the C1-building blocks carbon
monoxide and isocyanides provides heteroallenes (ie ketenes, isocyanates, ketenimines …

Carbodiimides are a unique class of heterocumulene compounds that display distinctive
chemical properties. The rich chemistry of carbodiimides has drawn increasing attention …

This focused review aims to summarize recent developments in the processes involving
additions of secondary propargylamines to various heteroallenes and subsequent transition …

The conjugated bis-guanidinate (CBG) supported zinc hydride,[{LZnH} 2; L={(ArHN)(ArN)-
C═ N–C═(NAr)(NHAr); Ar= 2, 6-Et2-C6H3}](1)(pre)-catalyzed addition of E–H (E= B, C, N …

Three symmetric N, N‐diarylformamidine dithiocarbamates, N, N′‐bis (2, 6‐
dimethylphenyl) formamidine dithiocarbamate (DTL1), N, N′‐bis (2, 6‐disopropylphenyl) …

The reactivity of [(dpp-Bian) Al (H) 2Li (THF) 3](1)(dpp-Bian= 1, 2-bis [(2, 6-
diisopropylphenyl) imino] acenaphthene) and [(ArBIG-Bian) Al (H) 2Li (THF) 4](2)(ArBIG …

1, 3-Phosphaazaallenes are heteroallenes of the type RPCNR′ and little is known about
their reactivity. In here we describe the straightforward synthesis of ArPCNR (Ar= Mes*, 2, 4 …

N-Heterocyclic carbenes (NHCs) are an important class of reactive organic molecules used
as ligands, organocatalysts, and σ-donors in a variety of electroneutral ylide or betaine …

The organoactinide‐catalyzed monohydroboration of carbodiimides is reported herein. The
catalytic reactions proceed under very mild conditions in a highly atom‐efficient and highly …

We report hydroboration of carbodiimide and isocyanate substrates catalyzed by a cyclic
carbodiphosphorane catalyst. The cyclic carbodiphosphorane outperformed the other Lewis …