Spin–phonon coupling and magnetic relaxation in single-molecule magnets

JGC Kragskow, A Mattioni, JK Staab, D Reta… - Chemical Society …, 2023 - pubs.rsc.org
Electron–phonon coupling is important in many physical phenomena, eg photosynthesis,
catalysis and quantum information processing, but its impacts are difficult to grasp on the …

Coherence in Chemistry: Foundations and Frontiers

JD Schultz, JL Yuly, EA Arsenault, K Parker… - Chemical …, 2024 - ACS Publications
Coherence refers to correlations in waves. Because matter has a wave-particle nature, it is
unsurprising that coherence has deep connections with the most contemporary issues in …

Quantum‐classical path integral evaluation of reaction rates with a near‐equilibrium flux formulation

A Bose, N Makri - International Journal of Quantum Chemistry, 2021 - Wiley Online Library
Quantum‐classical formulations of reactive flux correlation functions require the partial Weyl–
Wigner transform of the thermalized flux operator, whose numerical evaluation is unstable …

Quantum dynamical effects of vibrational strong coupling in chemical reactivity

LP Lindoy, A Mandal, DR Reichman - Nature Communications, 2023 - nature.com
Recent experiments suggest that ground state chemical reactivity can be modified when
placing molecular systems inside infrared cavities where molecular vibrations are strongly …

[BOOK][B] The Langevin equation: with applications to stochastic problems in physics, chemistry and electrical engineering

W Coffey, YP Kalmykov - 2012 - books.google.com
This volume is the third edition of the first-ever elementary book on the Langevin equation
method for the solution of problems involving the translational and rotational Brownian …

[HTML][HTML] Non-equilibrium reactive flux: A unified framework for slow and fast reaction kinetics

A Bose, N Makri - The Journal of Chemical Physics, 2017 - pubs.aip.org
The flux formulation of reaction rate theory is recast in terms of the expectation value of the
reactive flux with an initial condition that corresponds to a non-equilibrium, factorized …

Decoherence-induced surface hop**

HM Jaeger, S Fischer, OV Prezhdo - The Journal of chemical physics, 2012 - pubs.aip.org
A simple surface hop** method for nonadiabatic molecular dynamics is developed. The
method derives from a stochastic modeling of the time-dependent Schrödinger and master …

Tensor propagator for iterative quantum time evolution of reduced density matrices. I. Theory

N Makri, DE Makarov - The Journal of chemical physics, 1995 - pubs.aip.org
For common condensed phase problems described by a low‐dimensional system coupled
to a harmonic bath, Feynman's path integral formulation of time‐dependent quantum …

Resonance theory of vibrational strong coupling enhanced polariton chemistry and the role of photonic mode lifetime

W Ying, P Huo - Communications Materials, 2024 - nature.com
Recent experiments demonstrate polaritons under the vibrational strong coupling (VSC)
regime can modify chemical reactivity. Here, we present a complete theory of VSC-modified …

Tensor propagator for iterative quantum time evolution of reduced density matrices. II. Numerical methodology

N Makri, DE Makarov - The Journal of chemical physics, 1995 - pubs.aip.org
In a recent Letter [Chem. Phys. Lett. 221, 482 (1994)], we demonstrated that the dynamics of
reduced density matrices for systems in contact with dissipative harmonic environments can …