The fields of C–H functionalization and photoredox catalysis have garnered enormous
interest and utility in the past several decades. Many different scientific disciplines have …

The halogen-atom transfer (XAT) is one of the most important and applied processes for the
generation of carbon radicals in synthetic chemistry. In this review, we summarize and …

Radical/radical cross-coupling reactions represent an efficient and straightforward approach
for the construction of chemical bonds and accordingly have drawn increasing attention over …

Alkyl radicals are key intermediates in organic synthesis. Their classic generation from alkyl
halides has a severe drawback due to the employment of toxic tin hydrides to the point that …

As the “chemical chameleon”, sulfonyl-containing compounds and their variants have been
merged with various types of reactions for the efficient construction of diverse molecular …

Organoelectrophotocatalytic generation of acyl radicals from formamides and aldehydes to
synthesize acylated 3-CF3-2-oxindoles has been developed. This protocol features a …

Although carbon is the central element of organic chemistry, oxygen is the central element of
stereoelectronic control in organic chemistry. Generally, a molecule with a C–O bond has …

As a key element in the construction of complex organic scaffolds, the formation of C− C
bonds remains a challenge in the field of synthetic organic chemistry. Recent advancements …

A Markovnikov-selective hydroacylation of alkenes has been achieved via the synergistic
merger cobalt, photoredox and N-heterocyclic carbene catalysis. The closely incorporated …

The activation and transformation of carbon monoxide (CO), a versatile C1 feedstock,
continues to attract substantial attention. Traditionally, researchers have focused on the …