A very basic tutorial-style introduction to Single-Molecule Magnetism, intended for a general
chemistry audience, is provided. This is followed by a review of the synthesis, structures and …

A systematic study of the stereochemistry of the coordination sphere of transition metal
compounds has been carried out recently from the point of view of the continuous shape …

A reversible single-crystal-to-single-crystal transformation is used to dramatically change the
relaxation behavior of a single-ion magnet. The coordination geometry of the DyIII site of a …

The magnetic anisotropy associated with a pentagonal bipyramidal (PBP) coordination
sphere is examined on the basis of experimental and theoretical investigations. The origin …

A stereochemical study of polyhedral eight‐vertex structures is presented, based on
continuous shape measures (CShM). Reference polyhedra, shape maps, and minimal …

Although the development of single‐molecule magnets (SMMs) is rapid, there are only two
families of high energy barrier (Ueff) dysprosium (III) SMMs known so far: the …

A definition of minimum distortion paths between two polyhedra in terms of continuous
shape measures (CShM) is presented. A general analytical expression deduced for such …

A record anisotropy barrier (319 cm− 1) for all d‐f complexes was observed for a unique FeII‐
DyIII‐FeII single‐molecule magnet (SMM), which possesses two asymmetric and distorted …

The stereochemistry of nine‐coordinate transition‐metal and rare‐earth compounds has
been studied by means of continuous shape measures (CShM) and related tools. Several …

We generate a new air-stable pseudo-D5h Dy (III) Single-Molecule Magnet (Ueff= 1108 K,
TB= 14 K) by combining a weak equatorial ligand field from a macrocyclic LN5 ligand with a …