Organoboron reagents represent a unique class of compounds because of their utility in
modern synthetic organic chemistry, often affording unprecedented reactivity. The …

Conspectus Transition metal catalyzed asymmetric hydrofunctionalization of readily
available unsaturated hydrocarbons presents one of the most straightforward and atom …

Chiral organoboronates have played a critical role in organic chemistry and in the
development of materials science and pharmaceuticals. Much effort has been devoted to …

This paper reviewed the recent research progress of organic reactions catalyzed by four
typical earth-abundant and 3d metal catalysts: Mn, Fe, Co, and Ni complexes and mainly …

Bioisosteric replacement has emerged as a clear strategy for drug-structure optimization.
Naphthalene is the core element of many chiral pharmaceuticals and drug candidates …

Chiral boronic esters are a class of versatile building blocks. We describe herein an
asymmetric nickel-catalyzed borylative coupling of terminal alkenes with nonactivated alkyl …

One-pot reactions elaborated around transition metal-catalyzed isomerization of alkenes not
only offer the inherent advantages of atom-, step-and redox-economy but also enable the …

Transition‐metal‐catalyzed C− H functionalization reactions with Cp* MIII catalysts (M= Co,
Rh, Ir) have found a wide variety of applications in organic synthesis. Albeit the intrinsic …

The asymmetric cross-coupling reaction is developed as a straightforward strategy toward 1,
1-diaryl alkanes, which are a key skeleton in a series of natural products and bioactive …

Hydrofunctionalization of alkenes and alkynes is increasingly important in preparing and
modifying carbon-centered organic molecules such as pharmaceuticals, agrochemicals, and …