Theory and simulations of ionic liquids in nanoconfinement

S Kondrat, G Feng, F Bresme, M Urbakh… - Chemical …, 2023 - ACS Publications
Room-temperature ionic liquids (RTILs) have exciting properties such as nonvolatility, large
electrochemical windows, and remarkable variety, drawing much interest in energy storage …

Ionic liquids at electrified interfaces

MV Fedorov, AA Kornyshev - Chemical reviews, 2014 - ACS Publications
Until recently,“room-temperature”(< 100− 150 C) liquidstate electrochemistry was mostly
electrochemistry of diluted electrolytes 1− 4 where dissolved salt ions were surrounded by a …

Ionic liquids in confined geometries

S Perkin - Physical Chemistry Chemical Physics, 2012 - pubs.rsc.org
Over recent years the Surface Force Apparatus (SFA) has been used to carry out model
experiments revealing structural and dynamic properties of ionic liquids confined to thin …

Mean-field theory of electrical double layer in ionic liquids with account of short-range correlations

ZAH Goodwin, G Feng, AA Kornyshev - Electrochimica Acta, 2017 - Elsevier
We develop the theory of the electrical double layer in ionic liquids as proposed earlier by
Kornyshev (2007). In the free energy function we keep the so called 'short-range correlation …

Perspective: Coulomb fluids—Weak coupling, strong coupling, in between and beyond

A Naji, M Kanduč, J Forsman… - The Journal of chemical …, 2013 - pubs.aip.org
We present a personal view on the current state of statistical mechanics of Coulomb fluids
with special emphasis on the interactions between macromolecular surfaces, concentrating …

Ionic Coulomb blockade as a fractional Wien effect

N Kavokine, S Marbach, A Siria, L Bocquet - Nature nanotechnology, 2019 - nature.com
Recent advances in nanofluidics have allowed the exploration of ion transport down to
molecular-scale confinement, yet artificial porins are still far from reaching the advanced …

Breakdown of electroneutrality in nanopores

A Levy, JP de Souza, MZ Bazant - Journal of Colloid and Interface Science, 2020 - Elsevier
Ion transport in extremely narrow nanochannels has gained increasing interest in recent
years due to unique physical properties at the nanoscale and the technological advances …

Charge oscillations in ionic liquids: A microscopic cluster model

Y Avni, RM Adar, D Andelman - Physical Review E, 2020 - APS
In spite of their enormous applications as alternative energy storage devices and lubricants,
room-temperature ionic liquids (ILs) still pose many challenges from a pure scientific …

Structural interactions in ionic liquids linked to higher-order Poisson-Boltzmann equations

R Blossey, AC Maggs, R Podgornik - Physical Review E, 2017 - APS
We present a derivation of generalized Poisson-Boltzmann equations starting from classical
theories of binary fluid mixtures, employing an approach based on the Legendre transform …

The simplest model of charge storage in single file metallic nanopores

AA Kornyshev - Faraday Discussions, 2013 - pubs.rsc.org
The problem of voltage controlled accumulation of ions in a narrow nanopore, which can
accommodate just one row of ions of an ionic liquid and is filled with ions when the electrode …