London dispersion in molecular chemistry—reconsidering steric effects

JP Wagner, PR Schreiner - Angewandte Chemie International …, 2015 - Wiley Online Library
London dispersion, which constitutes the attractive part of the famous van der Waals
potential, has long been underappreciated in molecular chemistry as an important element …

Multiconfiguration self-consistent field and multireference configuration interaction methods and applications

PG Szalay, T Muller, G Gidofalvi, H Lischka… - Chemical …, 2012 - ACS Publications
The configuration interaction (CI) method is a general procedure to compute approximate
solutions to the electronic Schrödinger equation. The wave function is written as a linear …

[HTML][HTML] The ORCA quantum chemistry program package

F Neese, F Wennmohs, U Becker… - The Journal of chemical …, 2020 - pubs.aip.org
In this contribution to the special software-centered issue, the ORCA program package is
described. We start with a short historical perspective of how the project began and go on to …

An overlap fitted chain of spheres exchange method

R Izsák, F Neese - The Journal of chemical physics, 2011 - pubs.aip.org
The “chain of spheres”(COS) algorithm, as part of the RIJCOSX SCF procedure,
approximates the exchange term by performing analytic integration with respect to the …

A geometrical correction for the inter-and intra-molecular basis set superposition error in Hartree-Fock and density functional theory calculations for large systems

H Kruse, S Grimme - The Journal of chemical physics, 2012 - pubs.aip.org
A semi-empirical counterpoise-type correction for basis set superposition error (BSSE) in
molecular systems is presented. An atom pair-wise potential corrects for the inter-and intra …

Comprehensive benchmark results for the domain based local pair natural orbital coupled cluster method (DLPNO-CCSD (T)) for closed-and open-shell systems

DG Liakos, Y Guo, F Neese - The Journal of Physical Chemistry A, 2019 - ACS Publications
In this study we examine the accuracy of domain-based local pair natural orbital coupled
cluster theory with single, double, and perturbative triple excitations (DLPNO-CCSD (T)) on …

Stabilization and structure calculations for noncovalent interactions in extended molecular systems based on wave function and density functional theories

KE Riley, M Pitonák, P Jurecka, P Hobza - Chemical Reviews, 2010 - ACS Publications
More than 20 years ago, we published in Chemical ReViews a paper entitled
“Intermolecular Interactions between Medium-Sized Systems. Nonempirical and Empirical …

Efficient and accurate approximations to the local coupled cluster singles doubles method using a truncated pair natural orbital basis

F Neese, A Hansen, DG Liakos - The Journal of chemical physics, 2009 - pubs.aip.org
A production level implementation of the closed-shell local quadratic configuration
interaction and coupled cluster methods with single and double excitations (QCISD and …

Is it possible to obtain coupled cluster quality energies at near density functional theory cost? Domain-based local pair natural orbital coupled cluster vs modern …

DG Liakos, F Neese - Journal of chemical theory and computation, 2015 - ACS Publications
The recently developed domain-based local pair natural orbital coupled cluster theory with
single, double, and perturbative triple excitations (DLPNO-CCSD (T)) delivers results that …

Decomposition of intermolecular interaction energies within the local pair natural orbital coupled cluster framework

WB Schneider, G Bistoni, M Sparta… - Journal of chemical …, 2016 - ACS Publications
The local coupled cluster method DLPNO-CCSD (T) allows calculations on systems
containing hundreds of atoms to be performed while typically reproducing canonical CCSD …