Accelerating chemo-and regioselective hydrogenation of alkynes over bimetallic nanoparticles in a metal–organic framework

L Li, W Yang, Q Yang, Q Guan, J Lu, SH Yu… - ACS …, 2020 - ACS Publications
Selective semihydrogenation of alkynes has been a long-term and significant target, yet it
remains a great challenge. Herein, bimetallic nanoparticles in a metal–organic framework …

CO2 and H2 Activation on Zinc‐Doped Copper Clusters

B Zamora, L Nyulászi, T Höltzl - ChemPhysChem, 2024 - Wiley Online Library
Here we systematically investigate the CO2 and H2 activation and dissociation on small
CunZn0/+(n= 3–6) clusters using Density Functional Theory. We show that Cu6Zn is a …

Structures, stability and electronic properties of the NH3 adsorbed and embedded NiBm−1Nm (m = 48, 72 and 96) tubular clusters

J Li, Z Li, Z Zhao - Research on Chemical Intermediates, 2024 - Springer
The structures, stability and electronic properties of the Ni-doped boron nitride tubular
clusters (NiB m− 1N m), NH3 adsorption on the NiB m− 1N m (NH3NiB m− 1N m) and NH3 …

Ab Initio Insights into the Formation Mechanisms of 55-Atom Pt-Based Core–Shell Nanoalloys

PCD Mendes, SG Justo, J Mucelini… - The Journal of …, 2019 - ACS Publications
Platinum-based nanoalloys can yield unique properties due to synergistic effects derived
from the combination of Pt with one or more transition-metal (TM) species, as well as from …

Structures and stabilities Ru-doped Agn (n= 1–13) clusters: Ag10Ru a 18-ve cluster superatom

PL Rodríguez-Kessler, S Rodríguez-Carrera… - Inorganica Chimica …, 2025 - Elsevier
The geometrical and stability properties of Ru-doped silver clusters (Ag n Ru with n= 1–13)
are investigated by density functional theory (DFT) calculations. The results show that the Ru …

Electronic properties and adsorption mechanism of Ru-doped copper clusters towards CH3OH molecule: A DFT investigation

M Boulbazine, AG Boudjahem - Journal of Molecular Graphics and …, 2023 - Elsevier
In this study, we have investigated the stability and electronic properties of the Cu n Ru (n= 2–
10) nanoclusters and their interaction with the CH 3 OH molecule without and with the …

Structure evolution of Cu3Pd single-particles under CO2 hydrogenation

C Xu, S Han, Q Zhao, S Liu, W Liu, Y Li… - Chemical Engineering …, 2024 - Elsevier
Encapsulating metal nanoparticles into a porous silica shell, forming a core–shell geometry,
has been popularly applied to prevent the particles from sintering at the elevated …

Theoretical investigations on structural, electronic, adsorptive and catalytic properties of BiPdn (n= 2-20) bimetallic nanoclusters

SY Zhong, SY Wu, JX Guo, GQ Shen, XY Li… - Journal of Non-Crystalline …, 2022 - Elsevier
Through electrochemical reduction, toxic air pollutants (such as nitric oxide (NO) and carbon
monoxide (CO)) can be converted into less harmful gases N 2 O and CO 2. In this article, the …

[HTML][HTML] Probing the structural evolution, electronic and vibrational properties of neutral and anionic calcium-doped magnesium clusters

SH Liu, YJ Qi, YZ **, YY Wang, C Liu, P Sun… - Results in Physics, 2022 - Elsevier
Metallic clusters have received tremendous interest due to the unusual structure and
bonding along with potential as the motif for novel nanomaterials. Herein, the global …

First principle study on the interactions of Au(Ag2S)n (n = 1–8) with Hg0 and Hg2+

Z Tian, G Ma, N Zhang, C Song, C Teng - Journal of Nanoparticle …, 2024 - Springer
First principle study on the interactions of Au (Ag2S) n with Hg0 and Hg2+ have been carried
out. Au (Ag2S) n clusters can absorb Hg0 and Hg2+. As n increases, the structure of Au …