Stereochemical expression of ns2 electron pairs in metal halide perovskites

Y Fu, S **, XY Zhu - Nature Reviews Chemistry, 2021 - nature.com
Metal halide perovskites (MHPs) are characterized as strongly anharmonic and dynamic
lattices. While there is a consensus on the solvation-like polarization effect in these …

The significance of polarons and dynamic disorder in halide perovskites

MJ Schilcher, PJ Robinson, DJ Abramovitch… - ACS Energy …, 2021 - ACS Publications
The development of halide perovskite semiconductors led to various technological
breakthroughs in optoelectronics, in particular in the areas of photovoltaics and light-emitting …

Two-dimensional overdamped fluctuations of the soft perovskite lattice in CsPbBr3

T Lanigan-Atkins, X He, MJ Krogstad, DM Pajerowski… - Nature materials, 2021 - nature.com
Lead halide perovskites exhibit structural instabilities and large atomic fluctuations thought
to impact their optical and thermal properties, yet detailed structural and temporal …

Strongly anharmonic octahedral tilting in two-dimensional hybrid halide perovskites

M Menahem, Z Dai, S Aharon, R Sharma, M Asher… - ACS …, 2021 - ACS Publications
Recent investigations of two-dimensional (2D) hybrid organic–inorganic halide perovskites
(HHPs) indicate that their optical and electronic properties are dominated by strong coupling …

Diverging expressions of anharmonicity in halide perovskites

A Cohen, TM Brenner, J Klarbring, R Sharma… - Advanced …, 2022 - Wiley Online Library
Lead‐based halide perovskite crystals are shown to have strongly anharmonic structural
dynamics. This behavior is important because it may be the origin of their exceptional …

Contrasting Ultra-Low Frequency Raman and Infrared Modes in Emerging Metal Halides for Photovoltaics

VJY Lim, M Righetto, S Yan, JB Patel, T Siday… - ACS Energy …, 2024 - ACS Publications
Lattice dynamics are critical to photovoltaic material performance, governing dynamic
disorder, hot-carrier cooling, charge-carrier recombination, and transport. Soft metal-halide …

Nonlinear terahertz control of the lead halide perovskite lattice

M Frenzel, M Cherasse, JM Urban, F Wang, B **ang… - Science …, 2023 - science.org
Lead halide perovskites (LHPs) have emerged as an excellent class of semiconductors for
next-generation solar cells and optoelectronic devices. Tailoring physical properties by fine …

Surface-binding molecular multipods strengthen the halide perovskite lattice and boost luminescence

DH Kim, SJ Woo, CP Huelmo, MH Park… - Nature …, 2024 - nature.com
Reducing the size of perovskite crystals to confine excitons and passivating surface defects
has fueled a significant advance in the luminescence efficiency of perovskite light-emitting …

Enhancing the hot-phonon bottleneck effect in a metal halide perovskite by terahertz phonon excitation

F Sekiguchi, H Hirori, G Yumoto, A Shimazaki… - Physical Review Letters, 2021 - APS
We investigate the impact of phonon excitations on the photoexcited carrier dynamics in a
lead-halide perovskite CH 3 NH 3 PbI 3, which hosts unique low-energy phonons that can …

Optical control of exciton spin dynamics in layered metal halide perovskites via polaronic state formation

SA Bourelle, FVA Camargo, S Ghosh… - Nature …, 2022 - nature.com
One of the open challenges of spintronics is to control the spin relaxation mechanisms.
Layered metal-halide perovskites are an emerging class of semiconductors which possess a …