Highly confined water: two-dimensional ice, amorphous ice, and clathrate hydrates

WH Zhao, L Wang, J Bai, LF Yuan… - Accounts of chemical …, 2014 - ACS Publications
Conspectus Understanding phase behavior of highly confined water, ice, amorphous ice,
and clathrate hydrates (or gas hydrates), not only enriches our view of phase transitions and …

Temperature-pressure phase diagram of confined monolayer water/ice at first-principles accuracy with a machine-learning force field

B Lin, J Jiang, XC Zeng, L Li - Nature Communications, 2023 - nature.com
Understanding the phase behaviour of nanoconfined water films is of fundamental
importance in broad fields of science and engineering. However, the phase behaviour of the …

Quasi-one-dimensional hydrogen bonding in nanoconfined ice

P Ravindra, XR Advincula, C Schran… - Nature …, 2024 - nature.com
Abstract The Bernal-Fowler ice rules stipulate that each water molecule in an ice crystal
should form four hydrogen bonds. However, in extreme or constrained conditions, the …

New insights into the interactions between two‐dimensional ice and two‐dimensional materials

QH Thi, J Zhao, TH Ly - Droplet, 2023 - Wiley Online Library
Water is one of the most essential substances for life on Earth and plays a vital role in both
natural and technological processes. Recently, there has been growing interest in studying …

Two dimensional ice from first principles: Structures and phase transitions

J Chen, G Schusteritsch, CJ Pickard, CG Salzmann… - Physical review …, 2016 - APS
Despite relevance to disparate areas such as cloud microphysics and tribology, major gaps
in the understanding of the structures and phase transitions of low-dimensional water ice …

Evidence of formation of 1–10 nm diameter ice nanotubes in double-walled carbon nanotube capillaries

Y Liu, J Jiang, Y Pu, JS Francisco, XC Zeng - ACS nano, 2023 - ACS Publications
Water exhibits rich phase behaviors in nanoscale confinement. Since the simulation
evidence of the formation of single-walled ice nanotubes (INTs) in single-walled carbon …

First-principles molecular dynamics simulations of the spontaneous freezing transition of 2D water in a nanoslit

J Jiang, Y Gao, W Zhu, Y Liu, C Zhu… - Journal of the …, 2021 - ACS Publications
As with bulk ices, two-dimensional (2D) ices exhibit diverse crystalline structures, and the
majority of these 2D structures have been predicted based on classical molecular dynamics …

Non-continuum intercalated water diffusion explains fast permeation through graphene oxide membranes

S Jiao, Z Xu - ACS nano, 2017 - ACS Publications
Recent experimental studies have revealed unconventional phase and transport behaviors
of water confined within lamellar graphene oxide membranes, which hold great promise not …

Evidence of spontaneous formation of two-dimensional amorphous clathrates on superhydrophilic surfaces

Y Gao, S Wang, J Jiang, Y Liu… - Journal of the …, 2024 - ACS Publications
Clathrate hydrates reserved in the seabed are often dispersed in the pores of coarse-
grained sediments; hence, their formation typically occurs under nanoconfinement. Herein …

Dielectric ordering of water molecules arranged in a dipolar lattice

MA Belyanchikov, M Savinov, ZV Bedran… - Nature …, 2020 - nature.com
Intermolecular hydrogen bonds impede long-range (anti-) ferroelectric order of water. We
confine H2O molecules in nanosized cages formed by ions of a dielectric crystal. Arranging …