Divalent Organocopper Complexes: Masked Radicals for Effective Electrochemically Driven Atom Transfer Radical Addition
Copper-catalyzed electrochemical atom transfer radical addition (e ATRA) is an emerging
synthetic approach to C–C bond formation. This method hinges on an electrochemically …
synthetic approach to C–C bond formation. This method hinges on an electrochemically …
Electrocatalytic Atom Transfer Radical Addition with Turbocharged Organocopper (II) Complexes
M Naher, C Su, JR Harmer, CM Williams… - Inorganic …, 2023 - ACS Publications
The utility and scope of Cu-catalyzed halogen atom transfer chemistry have been exploited
in the fields of atom transfer radical polymerization and atom transfer radical addition, where …
in the fields of atom transfer radical polymerization and atom transfer radical addition, where …
Kinetico-Mechanistic Studies on a Reactive Organocopper (II) Complex: Cu–C Bond Homolysis versus Heterolysis
Organocopper (II) reagents are an unexplored frontier of copper catalysis. Despite being
proposed as reactive intermediates, an understanding of the stability and reactivity of the …
proposed as reactive intermediates, an understanding of the stability and reactivity of the …
Heteroleptic copper (i) complexes [Cu (dmp)(N^ P)] BF 4 for photoinduced atom-transfer radical addition reactions
YH Zhao, HY Li, DJ Young, X Cao, DL Zhu… - Dalton …, 2023 - pubs.rsc.org
Earth-abundant copper (I) coordination complexes of an imine-phosphine and a diimine
have been developed as visible-light photocatalysts. Reaction of [Cu (MeCN) 4] BF4 with …
have been developed as visible-light photocatalysts. Reaction of [Cu (MeCN) 4] BF4 with …
Macrocyclic Copper (II) Complexes as Catalysts for Electrochemically Mediated Atom Transfer
M Naher, C Su, JR Harmer, CM Williams… - Inorganic …, 2024 - ACS Publications
Copper-catalyzed electrochemical atom transfer radical addition (e ATRA) is a new method
for the creation of new C–C bonds under mild conditions. In this work, we have explored the …
for the creation of new C–C bonds under mild conditions. In this work, we have explored the …
Atom Transfer Radical Addition of Activated Primary Alkyl Chlorides Using In Situ Generated [Cp*RuII(Cl)(PR3)] Catalysts
NS van Leeuwen, S Mathew, CEJ van Lare… - …, 2024 - Wiley Online Library
Atom transfer radical addition (ATRA) of halogenated compounds with alkenes is well
established but primary alkyl chlorides are understudied because of the difficult C− Cl bond …
established but primary alkyl chlorides are understudied because of the difficult C− Cl bond …
Synthesis and Aerobic Oxidation of Perfluoroalkyl d10 Metal Complexes Supported by 2,7‐Dimethyl‐1,8‐Naphthyridine
Abstract The coordination chemistry of 2, 7‐dimethyl‐1, 8‐naphthyridine has been explored
with perfluoroalkyl d10 metals, CuI, ZnII, and AgI. This ligand was shown to form …
with perfluoroalkyl d10 metals, CuI, ZnII, and AgI. This ligand was shown to form …
Kinetico‐Mechanistic Studies of Cu (II)‐Mediated Cyclization of Imines via C− H Bond Activations
Herein, we focus on the kinetico‐mechanistic studies of a carboxylate and Cu (II)‐assisted
synthesis of imidazo [1, 5‐a] pyridines encompassing C (sp3)− H amination and cyclization …
synthesis of imidazo [1, 5‐a] pyridines encompassing C (sp3)− H amination and cyclization …