Conspectus The hydrogen evolution reaction (HER), oxygen evolution reaction (OER), and
oxygen reduction reaction (ORR) are involved in biological and artificial energy conversions …

Pendant amines play an invaluable role in chemical reactivity, especially for molecular
catalysts based on earth-abundant metals. As inspired by [FeFe]-hydrogenases, which …

The synthesis of renewable fuels from abundant water or the greenhouse gas CO2 is a
major step toward creating sustainable and scalable energy storage technologies. In the last …

The use of 3d metals in de/hydrogenation catalysis has emerged as a competitive field with
respect to “traditional” precious metal catalyzed transformations. The introduction of …

This review provides a comprehensive view of the application of first-row transition metals in
asymmetric hydrogenation and asymmetric transfer hydrogenation. The catalytic behavior of …

While hydrogen plays an ever-increasing role in modern society, nature has utilized
hydrogen since a very long time as an energy carrier and storage molecule. Among the …

Cobalt has become increasingly attractive in homogeneous catalysis because of its unique
characteristics and outstanding catalytic performance in addition to being cheap and earth …

Hydrogenase enzymes efficiently process H2 and protons at organometallic FeFe, NiFe, or
Fe active sites. Synthetic modeling of the many H2ase states has provided insight into …

The most fundamental concepts in chemistry are structure, energetics, reactivity and their
inter-relationships, which are indispensable for promoting chemistry into a rational science …

Transition metal hydrides play a critical role in stoichiometric and catalytic transformations.
Knowledge of free energies for cleaving metal hydride bonds enables the prediction of …