Catalytic transformation of biomass-derived furfurals to cyclopentanones and their derivatives: A review

S Dutta, NS Bhat - ACS omega, 2021 - ACS Publications
Furfural (FF) and 5-(hydroxymethyl) furfural (HMF) are well-recognized biomass-derived
chemical building blocks with established applications and markets for several of their …

Approaches to the synthesis of Pd/C catalysts with controllable activity and selectivity in hydrogenation reactions

RM Mironenko, OB Belskaya, VA Likholobov - Catalysis Today, 2020 - Elsevier
Carbon-supported palladium catalysts are widely used for hydrogenation of various organic
compounds in the fine chemical industry. The nanoscale geometry and electronic structure …

Mechanism of Pd/C-catalyzed hydrogenation of furfural under hydrothermal conditions

RM Mironenko, OB Belskaya, VP Talsi, VA Likholobov - Journal of catalysis, 2020 - Elsevier
Catalytic hydrogenation of furfural under hydrothermal conditions is of great importance and
has recently attracted huge attention as an approach to obtaining a wide range of valuable …

Water-mediated hydrogen spillover accelerates hydrogenative ring-rearrangement of furfurals to cyclic compounds

X Li, Z Tong, S Zhu, Q Deng, S Chen, J Wang, Z Zeng… - Journal of …, 2022 - Elsevier
Abstract Upgrading bioderived furfurals (furfural, 5-hydroxymethylfurfural) to
cyclopentanones (cyclopentanone, 3-hydroxymethylcyclopentanone) and cyclopentanols …

Bifunctional role of hydrogen in aqueous hydrogenative ring rearrangement of furfurals over Co@ Co-NC

X Li, L Zhang, R Zhou, S Chen, J Wang… - ACS Sustainable …, 2022 - ACS Publications
Bifunctional hydrogenation and acid catalysis in aqueous solvents over reduced metal-
supported solid acids is a common method for tandem reactions of biomass derivates …

Aqueous-phase hydrogenation of furfural over supported palladium catalysts: Effect of the support on the reaction routes

RM Mironenko, VP Talsi, TI Gulyaeva… - Reaction Kinetics …, 2019 - Springer
The effect of the support nature (different carbons, aluminum oxide, mixed MgAl oxide) on
the activity of palladium catalysts and on the reaction routes of aqueous-phase …

Catalytic activity of bimetallic (Ruthenium/Palladium) nano‐alloy decorated porous carbons toward reduction of toxic compounds

P Veerakumar, K Salamalai… - Chemistry–An Asian …, 2019 - Wiley Online Library
Chicken feather‐derived high‐surface‐area porous activated carbon (CFAC) material was
prepared using chemical activation. A new composite composed of Ru‐Pd nanoparticles …

Selective aqueous-phase hydrogenation of furfural to cyclopentanol over Ni-based catalysts prepared from Ni-MOF composite

H **a, J Li, C Chen, D Wu, J Ren, J Jiang… - Inorganic Chemistry …, 2021 - Elsevier
Metal-organic frameworks (MOFs) as an emerging class of porous materials exhibit some
unique advantages, including controllable composition, a large surface area, high porosity …

Aqueous-phase hydrogenation of furfural in the presence of supported metal catalysts of different types. A review

RM Mironenko, OB Belskaya, VA Likholobov - Doklady Physical Chemistry, 2023 - Springer
Hydrogenation of furfural in the presence of heterogeneous catalysts has recently attracted
increased interest as a method for the synthesis of oxygen-containing compounds of various …

Furfural to Cyclopentanone–a Search for Putative Oligomeric By‐products

R Baldenhofer, JP Lange, SRA Kersten… - …, 2024 - Wiley Online Library
We report here on the reductive rearrangement of biomass‐derived furfural to
cyclopentanone, a promising non‐fossil feedstock for fuels and chemicals. An underreported …