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Mechanism of Rh-catalyzed oxidative cyclizations: closed versus open shell pathways
Conspectus A conceptual theory for analyzing and understanding oxidative addition
reactions that form the cornerstone of many transition metal mediated catalytic cycles that …
reactions that form the cornerstone of many transition metal mediated catalytic cycles that …
Density functional theory calculations of Rh-β-diketonato complexes
Density functional theory (DFT) results on the geometry, energies and charges of selected
Rh-β-diketonato reactants, products and transition states are discussed. Various DFT …
Rh-β-diketonato reactants, products and transition states are discussed. Various DFT …
Influence of substituents on the reduction potential and pKa values of β-diketones tautomers: A theoretical study
Insight is provided into the reduction potential, pK a, energy of deprotonation and other
electronic properties of eleven keto-enol tautomers of β-diketone derivatives, using density …
electronic properties of eleven keto-enol tautomers of β-diketone derivatives, using density …
Redox potentials of ligands and complexes-a DFT approach
ABSTRACT A review of the limited literature concerned with theoretical ways to predict
experimentally measured redox potentials of ligands and complexes is presented …
experimentally measured redox potentials of ligands and complexes is presented …
Assessing dual Rh/Ru cascade catalysts in one-pot homogeneous synthesis of ethanol from syngas and methanol
The direct conversion of cheap syngas into value-added ethanol at an industrial scale is in
high demand. Herein we disclose a one-pot homogeneous homologation of methanol to …
high demand. Herein we disclose a one-pot homogeneous homologation of methanol to …
Electrochemical study of carbonyl phosphine β-diketonato rhodium (I) complexes
The electrochemical oxidation of a series of [Rh (RCOCHCOR′)(CO)(PPh 3)] complexes
studied in acetonitrile, containing 0.100 mol dm− 3 tetra-n-butylammonium …
studied in acetonitrile, containing 0.100 mol dm− 3 tetra-n-butylammonium …
Rhodium (triphenylphosphine) carbonyl-2, 4-dioxo-3-pentyl-4-decanyloxybenzoate: synthesis, electrochemistry and oxidative addition kinetics
The synthesis, electrochemistry and oxidative addition kinetics are presented for a new [Rh
(β-diketonato)(CO)(PPh3)] complex (2), of rhodium metal complexed with a β-diketonato …
(β-diketonato)(CO)(PPh3)] complex (2), of rhodium metal complexed with a β-diketonato …
[HTML][HTML] Density functional theory calculated data of the iodomethane oxidative addition to oligothiophene-containing rhodium complexes–importance of dispersion …
Electronic and free energy data of density functional theory calculated optimized geometries
of the reactants, transition state of the oxidative addition reaction and different reaction …
of the reactants, transition state of the oxidative addition reaction and different reaction …
Electrochemical study of β-diketonatobis (triphenylphosphite) rhodium (I) complexes
The electrochemical behaviour of the series of ten [Rh (RCOCHCOR′)(P (OPh) 3) 2]
complexes with R, R′= CF3, CF3 (1), CF3, CH3 (2), CF3, Ph (C6H5)(3), CF3, Fc …
complexes with R, R′= CF3, CF3 (1), CF3, CH3 (2), CF3, Ph (C6H5)(3), CF3, Fc …
Synthesis and characterization of rhodium (I) 2-methylcupferrate complexes and their kinetic behaviour in iodomethane oxidative addition
S Warsink, FG Fessha, W Purcell, JA Venter - Journal of Organometallic …, 2013 - Elsevier
A number of substituted monocarbonyl complexes [Rh (MeCupf)(CO)(PR3)](where R= Ph, p-
MeOph, p-Tol, o-Tol and Cy, MeCupf= N-nitroso-N-(2-methylphenyl) hydroxylaminato …
MeOph, p-Tol, o-Tol and Cy, MeCupf= N-nitroso-N-(2-methylphenyl) hydroxylaminato …