Reversible-deactivation radical polymerization (Controlled/living radical polymerization): From discovery to materials design and applications

N Corrigan, K Jung, G Moad, CJ Hawker… - Progress in Polymer …, 2020 - Elsevier
Reversible-deactivation radical polymerization (RDRP) processes, such as atom transfer
radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT) …

RAFT polymerization to form stimuli-responsive polymers

G Moad - Polymer Chemistry, 2017 - pubs.rsc.org
Stimuli-responsive polymers adapt to their surrounding environment. These polymers are
capable of responding to a variety of external stimuli, which include optical, electrical …

A guide to the synthesis of block copolymers using reversible-addition fragmentation chain transfer (RAFT) polymerization

DJ Keddie - Chemical Society Reviews, 2014 - pubs.rsc.org
The discovery of reversible-deactivation radical polymerization (RDRP) has provided an
avenue for the synthesis of a vast array of polymers with a rich variety of functionality and …

New polymer synthesis by nitroxide mediated living radical polymerizations

CJ Hawker, AW Bosman, E Harth - Chemical reviews, 2001 - ACS Publications
At first glance, radical polymerization may be considered a mature technology with millions
of tons of vinyl based homo-and copolymers being produced annually. This perception of …

Living radical polymerization by the RAFT process

G Moad, E Rizzardo, SH Thang - Australian journal of chemistry, 2005 - CSIRO Publishing
This paper presents a review of living radical polymerization achieved with thiocarbonylthio
compounds [ZC (= S) SR] by a mechanism of reversible addition–fragmentation chain …

Functional polymers from novel carboxyl-terminated trithiocarbonates as highly efficient RAFT agents

JT Lai, D Filla, R Shea - Macromolecules, 2002 - ACS Publications
Introduction. Recent development of controlled radical polymerization leads to the synthesis
of many welldefined architectures with predictable molecular weights. The most important …

[HTML][HTML] Radical addition–fragmentation chemistry in polymer synthesis

G Moad, E Rizzardo, SH Thang - Polymer, 2008 - Elsevier
This review traces the development of addition–fragmentation chain transfer agents and
related ring-opening monomers highlighting recent innovation in these areas. The major …

Synthesis and solution properties of zwitterionic polymers

AB Lowe, CL McCormick - Chemical reviews, 2002 - ACS Publications
Polymers containing ionic groups are among the most important classes of macromolecules.
These types of polymers range from naturally occurring biopolymers such as proteins and …

Advances in RAFT polymerization: the synthesis of polymers with defined end-groups

G Moad, YK Chong, A Postma, E Rizzardo, SH Thang - Polymer, 2005 - Elsevier
This paper provides an overview and discusses some recent developments in radical
polymerization with reversible addition–fragmentation chain transfer (RAFT polymerization) …

Macromolecular design via reversible addition–fragmentation chain transfer (RAFT)/xanthates (MADIX) polymerization

S Perrier, P Takolpuckdee - Journal of Polymer Science Part A …, 2005 - Wiley Online Library
Among the living radical polymerization techniques, reversible addition–fragmentation chain
transfer (RAFT) and macromolecular design via the interchange of xanthates (MADIX) …